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Structural, magnetic and dielectric study OF Fe2O3 nanoparticles obtained through exploding wire technique
Current Applied Physics ( IF 2.4 ) Pub Date : 2021-02-01 , DOI: 10.1016/j.cap.2020.11.009
Surendra Singh , Navendu Goswami

Abstract We propose an exploding wire technique based facile approach to prepare Fe2O3 nanoparticles in ambient conditions. TG-DSC analysis of the prepared precursor (Fe(OH)3) nanoparticles were done. The phase, lattice parameter and the average crystallite size were evaluated through X-ray diffraction analysis. The morphology of prepared nanoparticles was studied by scanning electron microscopy and Transmission electron microscope. The functional group formation of Fe2O3 nanoparticles and intrinsic stretching vibration bands of Fe–O were estimated through FTIR analysis. The direct band gap of Fe2O3 nanoparticles occurring in conjunction with indirect band gaps was established via Tauc plot. The magnetic parameters were studied through Mossbauer spectroscopy, ESR, M-H and M-T plot analysis. The attributes of dielectric behaviour like dielectric constant (e′), loss tangent (tan δ), dielectric loss (e″) and alternating current (AC) conductivity (σAC) were measured at various temperatures in the frequency range of 10 Hz-106 KHz.

中文翻译:

Fe2O3纳米粒子的结构、磁性和介电研究通过爆炸丝技术获得

摘要 我们提出了一种基于爆炸丝技术的简便方法来在环境条件下制备 Fe2O3 纳米颗粒。对制备的前体 (Fe(OH)3) 纳米粒子进行了 TG-DSC 分析。通过X射线衍射分析评估相、晶格参数和平均微晶尺寸。通过扫描电子显微镜和透射电子显微镜研究制备的纳米颗粒的形貌。通过 FTIR 分析估计 Fe2O3 纳米颗粒的官能团形成和 Fe-O 的固有伸缩振动带。Fe2O3 纳米粒子的直接带隙与间接带隙一起通过 Tauc 图建立。通过穆斯堡尔谱、ESR、MH 和 MT 图分析研究了磁参数。
更新日期:2021-02-01
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