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Composition dependence of amorphous forming, crystallization behaviors and magnetic properties in Fe-rich Fe-B-Cu-Hf alloys
Journal of Non-Crystalline Solids ( IF 3.5 ) Pub Date : 2020-12-03 , DOI: 10.1016/j.jnoncrysol.2020.120560
Meng Xiao , LiBao Zheng , Lin Zhou , Haoyang Yu , GuoTai Wang , DeChang Zeng

The effects of Si and/or P addition in amorphous Fe86+x(B12.5M0.5Cu0.4Hf0.6)14-x (M = P, Si; x = 0.2, 0.4 and 0.6) and Fe86+a(B12N1Cu0.4Hf0.6)14-a (N = PSi; P/Si = 3/1, 1/1 and 1/3; a = 0.2, 0.4 and 0.6) alloys on the amorphous forming ability, thermal stability and soft magnetic properties were investigated. The results indicated that Si had stronger effect on the AFA than that of P element. The increase of Si/P ratio enhanced the AFA. Both Si and/or P addition decreased the onset temperature of the first crystallization, meanwhile the decreased Si/P ratio resulted in higher thermal stability of the second crystallization. After optimal heat treatments, Bs and Hc of the Fe86.4(B12.5Si0.5Cu0.4Hf0.6)13.6 crystallized ribbons reached to 1.95 T and 3.1 A/m, that of the crystallized Fe86.4(B12P0.25Si0.75Cu0.4Hf0.6)13.6 ribbons were 1.98 T and 2.1 A/m, respectively. These materials are potentially applied in the high magnetic flux transaction fields.



中文翻译:

富铁的Fe-B-Cu-Hf合金的非晶形成,结晶行为和磁性能的成分依赖性

非晶态Fe 86+ x(B 12.5 M 0.5 Cu 0.4 Hf 0.614- x(M = P,Si; x  = 0.2、0.4和0.6)和Fe 86+ a(B中添加Si和/或P的影响12 N 1 Cu 0.4 Hf 0.614- a(N = PSi; P / Si = 3/1,1/1 and 1/3; a  = 0.2,0.4 and 0.6)合金的非晶形成能力,热稳定性和研究了软磁性能。结果表明,硅对AFA的作用更强。比P元素 Si / P比的增加提高了AFA。Si和/或P的添加均降低了第一结晶的开始温度,同时降低的Si / P比导致第二结晶的更高的热稳定性。经过最佳热处理后,Fe 86.4(B 12.5 Si 0.5 Cu 0.4 Hf 0.613.6结晶带的B sH c达到1.95 T和3.1 A / m,而Fe 86.4(B 12 P 0.25 Si 0.750.4 Hf0.613.6色带分别为1.98 T和2.1 A / m。这些材料潜在地应用于高磁通量交易领域。

更新日期:2020-12-04
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