Inorganic and Nano-Metal Chemistry ( IF 1.7 ) Pub Date : 2020-12-02 , DOI: 10.1080/24701556.2020.1852255 Man-Sheng Chen 1, 2 , Xiao-Jie Li 1, 2 , Yi-Fang Deng 1, 2 , Chun-Hua Zhang 1, 2 , Liang-Bing Sheng 1, 2 , Wei-Hong Lu 1, 2
Abstract
A new 3D coordination polymer, [Co2(MIP)2(BMIP)]n (1), [H2MIP = 5-methyl-isophthalic acid, BMIP = 1,5-bis-(2-methyl-imidazol)pentane] has been synthesized and characterized by single crystal X-ray diffraction analysis. The results of structural analyses show that 1 has a two-fold interpenetrated 3D network with a pcu topology. In addition, the luminescent, electrochemical properties and degradation of MB and MO of the complex were studied. The photocatalytic mechanism was proposed and confirmed by trapping experiments of radical species.
中文翻译:
一种新的 3D 二维钴基配位框架的水热合成、结构和性能
摘要
一种新的 3D 配位聚合物,[Co 2 (MIP) 2 (BMIP)] n ( 1 ),[H 2 MIP = 5-甲基-间苯二甲酸,BMIP = 1,5-双-(2-甲基-咪唑)戊烷] 已合成并通过单晶 X 射线衍射分析表征。结构分析结果表明,1具有具有pcu拓扑结构的两重互穿 3D 网络。此外,还研究了配合物的发光、电化学性能和MB和MO的降解。通过自由基物种的捕获实验提出并证实了光催化机理。