Porous Cu-doped alumina (P-Cu-Al₂O₃) has been synthesized using ammonium chloride as a green gaseous template. The unique pore-forming agent endows the catalyst a large surface area and homogenous pore structure. According to the characterization results by multi-technologies, the highly dispersed framework Cu⁺/Cu²⁺ was incorporated in octahedral sites with the formation of the Cu-O-Al bonds. Compared with bulk Cu-doped Al₂O₃ (B-Cu-Al₂O₃), more surface acidic oxygen-containing groups and Lewis acid sites existed in P-Cu-Al₂O₃, resulting in the production of surface adsorbed ^•OH, which is helpful for the removal of surface adsorbed organic intermediates. In addition, O₂ more easily participate in surface reaction to promote the ^•OH generation in P-Cu-Al₂O₃ system than that in B-Cu-Al₂O₃. As a result, the representative endocrine disruptor bisphenol A can be more efficiently mineralized by P-Cu-Al₂O₃. This work provides a facile route to develop porous active heterogenous Fenton-like catalysts and a unique perspective to insight into the structure-activity relationship.

已经使用氯化铵作为绿色气态模板合成了多孔掺杂铜的氧化铝（P-Cu-Al ₂ O ₃）。独特的成孔剂使催化剂具有较大的表面积和均匀的孔结构。根据多种技术的表征结果，高度分散的骨架Cu ⁺ / Cu ²⁺被引入八面体部位，形成Cu-O-Al键。与块状Cu掺杂Al ₂ O ₃（B-Cu-Al ₂ O ₃）相比，P-Cu-Al ₂ O _3中存在更多的表面酸性含氧基团和路易斯酸位，从而产生表面吸附的^• OH，有助于去除表面吸附的有机中间体。此外，O- ₂更容易参与表面反应促进^• OH产生在P-铜铝₂ ö ₃系统比B-铜铝₂ ö ₃。结果，代表性的内分泌干扰物双酚A可以被P-Cu-Al ₂ O ₃更有效地矿化。这项工作提供了开发多孔活性均相Fenton状催化剂的简便途径，并且为洞悉结构与活性之间的关系提供了独特的视角。