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CoFe-based layered double hydroxide for high removal capacity of hydrogen sulfide under high humid gas stream
Chemical Engineering Journal ( IF 15.1 ) Pub Date : 2020-12-02 , DOI: 10.1016/j.cej.2020.127918
Seongwoo Lee , Muthuraman Govindan , Daekeun Kim

Although the adsorption method was considered as the most realistic way in the removal of gaseous hydrogen sulfide (H2S), finding an efficient sorbent at low temperature with the high humid condition is still desired. A layered double hydroxide (LDH) of CoFe bimetal was prepared by co-precipitation of bivalent cobalt and trivalent iron and applied to H2S gas stream treatment. CoFe-LDH was optimally synthesized under 3:1 of Co/Fe molar ratio, pH 10 of a mixing solution of precipitating reagents, and 60°C of aging temperature, which allowed high breakthrough capacity (0.209 g H2S/g) in H2S removal. XPS and spectral analyses on spent CoFe-LDH proved that the H2S removal proceeded through two reaction processes: formed intermediate HS- from dissociated H2S which finally replaced with the hydroxide on the metal surface; and formed HS- through carbonate counter ion at interlayer. This resulted in the formation of CO2 as a gaseous product with CoFeS2 and CoFeSO4 as solid products after the treatment of H2S. Environmental application evidenced the prepared CoFe-LDH more efficient in high humid (90% relative humidity (RH) at room temperature) condition and even at high concentrated H2S source (3333 ppm).



中文翻译:

CoFe基层状双氢氧化物,在高湿气流下具有较高的硫化氢去除能力

尽管吸附方法被认为是去除气态硫化氢(H 2 S)的最现实的方法,但仍需要在低温和高湿度条件下找到有效的吸附剂。通过二价钴和三价铁的共沉淀制备CoFe双金属的层状双氢氧化物(LDH),并将其应用于H 2 S气流处理。在Co / Fe摩尔比为3:1,沉淀剂混合溶液的pH为10以及时效温度为60°C的条件下最佳合成了CoFe-LDH,这使得在Co中的高穿透能力(0.209 g H 2 S / g)成为可能。 H 2 S去除。XPS和对废CoFe-LDH的光谱分析证明了H 2小号去除通过两个反应流程进行:形成的中间HS -从解离ħ 2 S的最后与金属表面上的氢氧化取代; 和形成HS -通过在层间碳酸抗衡离子。经过H 2 S处理后,形成了以气态产物形式形成CO 2以及以CoFeS 2和CoFeSO 4作为固态产物。环保应用表明,所制备的CoFe-LDH在高湿度(90%相对湿度(RH))下更有效在室温下),甚至在高浓度的H 2 S源(3333 ppm)下。

更新日期:2020-12-02
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