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Strategy to Construct 1,2,3‐Triazoles by K2CO3‐Mediated [4+1] Annulation Reactions of N‐Acetyl Hydrazones with Bifunctional Amino Reagents
Advanced Synthesis & Catalysis ( IF 5.4 ) Pub Date : 2020-11-30 , DOI: 10.1002/adsc.202001375
Xiaoke Zhang 1, 2, 3 , Yang Pan 1, 3 , Haibo Wang 1, 3, 4 , Chong Liang 1 , Xiaofeng Ma 1 , Wei Jiao 1 , Huawu Shao 1
Affiliation  

K2CO3‐mediated [4+1] annulation reactions of N‐acetyl hydrazones with bifunctional amino reagents are described, which provide an environmental‐friendly strategy to construct 1,2,3‐triazoles that does not employ metals, azides, organocatalysis, or oxidants. A series of substituted 1,2,3‐triazole derivatives was prepared with good yields.

中文翻译:

K2CO3介导的N-乙酰Hy与双功能氨基试剂的[4 + 1]环化反应构造1,2,3-三唑的策略

描述了N乙酰基hydr与双功能氨基试剂的K 2 CO 3介导的[4 + 1]环化反应,这为构建不使用金属,叠氮化物,有机催化的1,2,3-三唑提供了环境友好的策略或氧化剂。以高收率制备了一系列取代的1,2,3-三唑衍生物。
更新日期:2021-01-19
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