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Near infrared light-driven release of pesticide with magnetic collectability using gel-based nanocomposite
Chemical Engineering Journal ( IF 15.1 ) Pub Date : 2020-11-30 , DOI: 10.1016/j.cej.2020.127881
Lihong Zhang , Siyi Ren , Chaowen Chen , Dongfang Wang , Bin Liu , Dongqing Cai , Zhengyan Wu

A near infrared light (NIRL)-driven release imidacloprid (NDRI) with magnetic collectability property was constructed using agarose hydrogel (AG), CuS-polydopamine (CP), zeolitic imidazolate framework-8 (ZIF-8), imidacloprid (IM), and ferriferrous oxide (Fe3O4). Therein, ZIF-8 with a large specific surface area was used to efficiently load IM molecules. CP, as a photothermal agent, could soften AG and enlarge the pores in hydrogel spheres under NIRL, resulting in the release of IM. After release, Fe3O4 was beneficial to conveniently collect the remaining NDRI from water. Additionally, the AG hydrogel with a porous structure acted as a good carrier for NDRI. Importantly, NDRI possessed an outstanding controlled-release property and could be reutilized at least for four times. Consequently, this technology may provide a potential approach to control release of IM, improve utilization efficiency, and decline pesticide usage and contamination to environment.



中文翻译:

凝胶基纳米复合材料的近红外光驱使具有磁性的农药释放

使用琼脂糖水凝胶(AG),CuS-聚多巴胺(CP),沸石咪唑啉骨架8(ZIF-8),吡虫啉(IM),和氧化亚铁(Fe 3 O 4)。其中,具有大的比表面积的ZIF-8被用于有效地装载IM分子。CP作为一种光热剂,可以在NIRL下软化AG并扩大水凝胶球体中的孔,导致IM的释放。释放后,Fe 3 O 4有利于方便地从水中收集剩余的NDRI。此外,具有多孔结构的AG水凝胶可作为NDRI的良好载体。重要的是,NDRI具有出色的控释特性,并且至少可以重复使用四次。因此,该技术可能提供一种控制IM释放,提高利用效率并减少农药使用和对环境污染的潜在方法。

更新日期:2020-12-01
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