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Influence of the 8-quinolinol concentration and solution pH on the interfacial properties of self-healing hydrotalcite coating applied to AZ31 magnesium alloy
Materials Today Communications ( IF 3.8 ) Pub Date : 2020-11-30 , DOI: 10.1016/j.mtcomm.2020.101923
Muhammad Junaid Anjum , Jingmao Zhao , Mohammad Tabish , Hassan Murtaza , Vahdat Zahedi Asl , Qiuxiang Yang , Muhammad Uzair Malik , Hamid Ali , Ghulam Yasin , Waheed Qamar Khan

The hydrotalcite-like (HT) coatings can provide an enhanced interfacial barrier to protect Mg alloys from corrosion. Therefore, 8-quinolinol (8Q), a green corrosion inhibitor, was intercalated in MgAl-based HT with varying concentration and pH values. The results revealed that the corrosion resistance was significantly improved when the pH of the solution was maintained at 10 with a 0.30 M concentration of 8Q. The hydrophobicity was also introduced to MgAl HT with the intercalation of 8Q, which was retained even after the long immersion. Furthermore, the self-healing performance of 8Q-intercalated HT was confirmed by single-frequency electrochemical impedance spectroscopy (EIS), which is a suitable method for in-situ evaluation of self-healing herein reported for the first time to evaluate the HT coatings. This thorough investigation of the hydrophobic MgAl HT coating is meaningfully supportive for researchers and engineers to have a deep understanding of its possibility for real-world applications in the area of corrosion and prevention.



中文翻译:

8-喹啉醇浓度和溶液pH值对AZ31镁合金自修复水滑石涂层界面性能的影响

类水滑石(HT)涂层可提供增强的界面屏障,以保护镁合金免受腐蚀。因此,绿色缓蚀剂8-喹啉醇(8Q)插入了具有不同浓度和pH值的基于MgAl的HT中。结果表明,当溶液的pH值保持在10且0.30 M浓度为8Q时,耐蚀性得到了显着改善。疏水性也通过插入8Q引入到MgAl HT中,即使长时间浸泡也可以保留。此外,通过单频电化学阻抗谱(EIS)证实了8Q嵌入的HT的自修复性能,这是本文首次报道的用于评估HT涂层的自修复的合适方法。 。

更新日期:2020-12-01
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