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Reaction between Ag17+ and acetylene outside the mass spectrometer: dehydrogenation in the gas phase
Chemical Communications ( IF 4.9 ) Pub Date : 2020-11-20 , DOI: 10.1039/d0cc05837h
Madhuri Jash 1, 2, 3, 4, 5 , Rabin Rajan J. Methikkalam 1, 2, 3, 4, 5 , Mohammad Bodiuzzaman 1, 2, 3, 4, 5 , Ganesan Paramasivam 1, 2, 3, 4, 5 , Thalappil Pradeep 1, 2, 3, 4, 5
Affiliation  

We present the first example of acetylide protected silver clusters by a reaction between Ag17+ and acetylene, conducted around atmospheric pressure. The products were obtained after dehydrogenation of acetylene in the gas phase. The observed reaction mechanism may be helpful to design new catalysts useful in organometallic chemistry.

中文翻译:

质谱仪外部Ag17 +与乙炔之间的反应:气相脱氢

我们通过在大气压下进行的Ag 17 +与乙炔之间的反应,给出了乙炔保护的银簇的第一个例子。在气相中乙炔脱氢后获得产物。观察到的反应机理可能有助于设计用于有机金属化学的新型催化剂。
更新日期:2020-11-27
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