当前位置: X-MOL 学术Minerals › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Odikhinchaite, Na9Sr3[(H2O)2Na]Ca6Mn3Zr3NbSi (Si24O72)O(OH)3(CO3)·H2O, a New Eudialyte-Group Mineral from the Odikhincha Intrusion, Taimyr Peninsula, Russia
Minerals ( IF 2.5 ) Pub Date : 2020-11-27 , DOI: 10.3390/min10121062
Yuliya D. Gritsenko , Nikita V. Chukanov , Sergey M. Aksenov , Igor V. Pekov , Dmitry A. Varlamov , Leonid A. Pautov , Svetlana A. Vozchikova , Dmitry A. Ksenofontov , Sergey N. Britvin

The new eudialyte-group mineral, odikhinchaite, was discovered in a peralkaline pegmatite vein hosted by melteigite at the Odikhincha ultrabasic alkaline–carbonatite intrusion, Taimyr Peninsula, Krasnoyarsk Krai, Russia. Associated minerals are orthoclase, albite, aegirine, cancrinite, ancylite-(Ce), catapleiite, and wadeite. Odikhinchaite occurs as dense rosette-like aggregates up to 11 mm across, consisting of split lamellar individuals. The mineral is translucent to transparent, deep purple, with vitreous luster. Odikhinchaite is brittle, with uneven fracture; distinct cleavage on (001) is observed. Hardness determined by the micro-indentation method is equal to 430 kgf/mm2; the Mohs hardness is 5. D(meas.) is 2.97(1) g·cm−3, D(calc.) is 3.04 g·cm–3. Odikhinchaite is optically uniaxial (–), ω = 1.638(2), ε = 1.630(2). The IR spectrum shows the presence of the IVMn2+O4 polyhedra, H2O molecules and CO32– anions. The chemical composition is (electron microprobe, H2O determined by the modified Penfield method, CO2 determined by selection sorption of gaseous annealing products; wt%): Na2O 9.25, K2O 0.59, CaO 12.77, MnO 5.49, FeO 0.75, MgO 0.24, La2O3 0.38, Ce2O3 0.39, Nd2O3 0.15, Al2O3 0.07, SiO2 44.80, ZrO2 11.13, TiO2 0.07, Nb2O5 4.17, Cl 0.69, CO2 0.90, H2O 2.22, –O = Cl –0.16, total 99.72. The crystal structure was solved using single-crystal X-ray diffraction data. Odikhinchaite is trigonal, space group R3m; the unit-cell parameters are: a = 14.2837(2) Å, c = 30.0697(3) Å, V = 5313.04(12) Å3. The new mineral is isostructural with other 12-layered members of the eudialyte group with the space group R3m. Its crystal chemical formula is (Z = 3): {N1(Na2.58Ca0.42)N2[Na2.37Ca0.51(H2O)0.12]N3(Sr2.00K0.45Na0.35REE0.20)N4Na3N5[(H2O)1.8Na1.2]}{ZZr3M1Ca6M2(Mn2.49Fe2+0.51)[M3Nb(OH)1.82O1.18](M4SiOH)[Si3O9]2[Si9O27]2X1[(CO3)0.53Cl0.47]X2[(H2O)0.6(O,F)0.4]XM4(CO3)0.15. The strongest lines of the powder X-ray diffraction pattern [d, Å (I, %) (hkl)] are: 11.42 (64) (101), 4.309 (41) (205), 3.405 (53) (131), 3.208 (45) (208, 036), 3.167 (44) (217), 2.978 (100) (315), 2.858 (86) (404).

中文翻译:

Odikhinchaite,Na9Sr3 [(H2O)2Na] Ca6Mn3Zr3NbSi(Si24O72)O(OH)3(CO3)·H2O,一种来自俄罗斯泰米尔半岛的Odikhincha侵入体的新型优地亚族矿物

在俄罗斯克拉斯诺亚尔斯克边疆区的泰米尔半岛超轻碱性碱-碳酸盐岩侵入体的奥迪金察超碱性碱性碳酸盐岩侵入岩中,一种由辉绿岩包裹的高碱性伟晶岩脉中发现了一种新的常绿辉石族矿物odikhinchaite。伴生矿物是原长石,钠长石,a石,斜方晶石,红柱石-(Ce),黑闪石和辉石。Odikhinchaite以密集的玫瑰花状聚集体形式出现,跨度达11毫米,由分裂的层状个体组成。矿物为半透明至透明,深紫色,具有玻璃光泽。Odikhinchaite脆,断裂不均匀。在(001)上观察到明显的切割。通过微压痕法测定的硬度等于430kgf / mm 2。莫氏硬度为5 d(测量)为2.97(1)克·厘米-3d(计算)为3.04 g·cm –3。Odikhinchaite是光学单轴(–),ω= 1.638(2),ε= 1.630(2)。红外光谱表明存在IV Mn 2+ O 4多面体,H 2 O分子和CO 3 2–阴离子。化学成分为(电子微探针,通过改进的Penfield方法确定的H 2 O,通过气态退火产物的选择性吸附确定的CO 2 ; wt%):Na 2 O 9.25,K 2 O 0.59,CaO 12.77,MnO 5.49,FeO 0.75,MgO 0.24,La 2 O 3 0.38,Ce 2 O 3 0.39,Nd 2O 3 0.15,Al 2 O 3 0.07,SiO 2 44.80,ZrO 2 11.13,TiO 2 0.07,Nb 2 O 5 4.17,Cl 0.69,CO 2 0.90,H 2 O 2.22,–O = Cl –0.16,总计99.72。使用单晶X射线衍射数据解析晶体结构。Odikhinchaite是三角形的,空间群R 3 m;晶胞参数为:一个= 14.2837(2)埃,c ^ = 30.0697(3)A,V = 5313.04(12)埃3。新矿物与同质异形体群的其他12层成员具有同构结构,空间群R 3 m。其晶体化学式为(Z = 3):{ N 1(Na 2.58 Ca 0.42N 2 [Na 2.37 Ca 0.51(H 2 O)0.12 ] N 3(Sr 2.00 K 0.45 Na 0.35 REE 0.20N 4 Na 3 N 5 [(H 2 O)1.8 Na1.2 ]} { Z Zr 3 M 1 Ca 6 M 2(Mn 2.49 Fe 2+ 0.51)[ M 3 Nb(OH)1.82 O 1.18 ](M 4 SiOH)[Si 3 O 9 ] 2 [Si 9 O 27 ] 2 X 1 [(CO 30.53 Cl 0.47 ] X 2 [(H 2 O)0.6(O,F)0.4 ] XM4(CO 30.15。粉末X射线衍射图的最强线[ d,Å(I,%)(hkl)]为:11.42(64)(101),4.309(41)(205),3.405(53)(131), 3.208(45)(208,036),3.167(44)(217),2.978(100)(315),2.858(86)(404)。
更新日期:2020-11-27
down
wechat
bug