This review article deals with organic synthesis from the perspective of selenium‐77 nuclear magnetic resonance (NMR) spectroscopy. Different types of organic reactions are briefly discussed, incorporating mechanism aspects through ⁷⁷Se NMR observable intermediates and by‐products. The ⁷⁷Se NMR experiments are demonstrated in terms of structural characterization and new insights for organic reactions. The ability to visualize different molecules in a reaction mixture provides a facile and versatile route for the development of synthetic organoselenium compounds. Thus, the review describes the strategies accomplished mainly in the past five years in the syntheses and applications of the organoselenium compounds, focusing on ⁷⁷Se NMR spectroscopy.

中文翻译：

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有机合成中的硒核磁共振谱：从结构表征到新研究

这篇综述文章从硒77核磁共振（NMR）光谱的角度探讨了有机合成。简要讨论了不同类型的有机反应，并通过⁷⁷ Se NMR观察到的中间体和副产物结合了机理方面的内容。通过结构表征和有机反应的新见解证明了⁷⁷ Se NMR实验。可视化反应混合物中不同分子的能力为合成有机硒化合物的开发提供了简便而通用的途径。因此，本综述描述了在过去五年中有机硒化合物的合成和应用中主要完成的策略，重点是⁷⁷ Se NMR光谱。