当前位置: X-MOL 学术Int. J. Hydrogen Energy › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Anion exchange membranes composed of quaternized polybenzimidazole and quaternized graphene oxide for glucose fuel cell
International Journal of Hydrogen Energy ( IF 7.2 ) Pub Date : 2020-11-27 , DOI: 10.1016/j.ijhydene.2020.11.043
Sairung Changkhamchom , Pongthorn Kunanupatham , Katesara Phasuksom , Anuvat Sirivat

Glucose is one of derivative products from agriculture, possessing high theoretical energy density, non-toxicity and ease of storage, which has been of interest as a fuel in glucose fuel cell. In this work, quaternized polybenzimidazole (Q-PBI) and quaternized graphene oxide (Q-GO) were successfully functionalized by the quaternization between polybenzimidazole (PBI) and 3-bromopropyl trimethylammonium bromide (3-Br), and the reaction between graphene oxide (GO) and dimethyloctadecyl [3(Trimethoxysilyl) propyl]ammonium chloride (DMAOP), respectively. The Q-GOs with various volume fractions were embedded as the dispersed phase in the Q-PBI matrix to produce the Q-GO/Q-PBI composites as an AEM. The 0.5%v/vQ-GO/Q-PBI composite AEM showed the highest hydroxide conductivity of 1.12 ± 0.01 mS cm−1 at 27 °C, the ion exchange capacity of 1.70 ± 0.03 mmol·g−1, the water uptake of 66.61 ± 0.57%, and the glucose permeability of (1.79 ± 0.83) × 10−8 cm2·s−1. The hydroxide conductivity was higher than the commercial Fumasep® FAB-PK-130 by a factor of 23 times, whereas the glucose permeability was lower by at least an order of magnitude.



中文翻译:

季铵化聚苯并咪唑和季铵化氧化石墨烯组成的用于葡萄糖燃料电池的阴离子交换膜

葡萄糖是农业衍生产品之一,具有较高的理论能量密度,无毒且易于储存,作为葡萄糖燃料电池中的燃料已引起人们的关注。在这项工作中,通过聚苯并咪唑(PBI)和3-溴丙基三甲基溴化铵(3-Br)之间的季铵化作用以及氧化石墨烯( GO)和二甲基十八烷基[3(三甲氧基甲硅烷基)丙基]氯化铵(DMAOP)。将具有不同体积分数的Q-GOs作为分散相嵌入Q-PBI基质中,以生产作为AEM的Q-GO / Q-PBI复合材料。0.5%v / vQ-GO / Q-PBI复合材料AEM的最高氢氧化物电导率为1.12±0.01 mS cm -1在27℃下,离子交换容量为1.70±0.03mmol·g -1,吸水率为66.61±0.57%,葡萄糖透过率为(1.79±0.83)×10 -8  cm 2 ·s -1。氢氧化物的电导率比市售的Fumasep®FAB-PK-130高出23倍,而葡萄糖的渗透率则降低了至少一个数量级。

更新日期:2020-11-27
down
wechat
bug