As a typical group of coordination polymers, metal–organic zeolite (MOZs) frameworks inherit the topological and structural advantages of inorganic zeolites and display great application potential in many areas, including gas adsorption/separation, catalysis, luminescence and chemical sensing. In this review, we outline the recent progress in the synthesis, functionalization and application of metal–organic zeolite frameworks, mainly focusing on the basic structural design principle and synthesis strategy on 4-connect inorganic nodes and 2-connect organic linkers. Employing different valent metals, small inorganic TO₄²⁻ units and high-nuclear clusters as 4-connect nodes, we derived multi-types of MOZs with a modified framework charge, improved stability and enhanced photo-/eletrocatalytic activity. Besides, the selection, functionalization and defect-engineering on the 2-connect ligands generated different topological and functional MOZs. Finally, the future trends and some perspectives in this area are outlined.

中文翻译：

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金属有机沸石（MOZ）框架结构设计的最新进展和观点

作为典型的配位聚合物，金属有机沸石（MOZ）骨架继承了无机沸石的拓扑和结构优势，并在许多领域显示出巨大的应用潜力，包括气体吸附/分离，催化，发光和化学传感。在这篇综述中，我们概述了金属-有机沸石骨架在合成，功能化和应用方面的最新进展，主要集中在4连接无机节点和2连接有机连接体的基本结构设计原理和合成策略上。采用不同的价金属，小的无机TO ₄ ^2-单元和高核簇作为4个连接节点，我们推导了多种类型的MOZ，它们具有改进的骨架电荷，提高的稳定性和增强的光催化/电催化活性。此外，对2-连接配体的选择，功能化和缺陷工程化产生了不同的拓扑和功能MOZ。最后，概述了该领域的未来趋势和一些观点。