This paper concentrates on the optical properties of cobalt borate glasses. A glass system 62B₂O₃ + 18Na₂O + (20-y) ZnO + (y) CoO where y = 0.5, 1.0 and 1.5 mol.% was produced by the melt-quenching method. Traditional techniques and standard formulas were used to determine the average density (ρ) and molar volume (V_m). Optical spectra were recruited, in terms of absorbance, to study the ligand field parameters in all glasses. The optical band gap (E_g) and phonon energy (E_ph) showed increasing behaviors with the increment in the content of Co cations. The obtained values of 10Dq/B point to a slight increment toward the strong crystal field. The average density showed increasing behavior and molar volume showed an opposite behavior with increasing Co cations. Moreover, the structural parameters in terms of interatomic separation were employed to study the increment toward the strong crystal field with the increment in the content of Co cations.

本文着重研究硼酸钴玻璃的光学性能。 通过熔融淬火法制得玻璃体系62B ₂ O ₃  + 18Na ₂ O +（20-y）ZnO +（y）CoO，其中y＝ 0.5、1.0和1.5摩尔％。使用传统技术和标准公式确定平均密度（ρ）和摩尔体积（V _m）。就吸光度而言，招募光谱来研究所有玻璃中的配体场参数。光学带隙（E _g）和声子能量（E _ph）显示出随着Co阳离子含量的增加而增加的行为。所获得的10Dq / B值指向强晶体场略有增加。平均密度显示出增加的行为，而摩尔体积显示出与Co阳离子增加相反的行为。此外，采用原子间分离的结构参数研究了随着Co阳离子含量的增加向强晶场的增加。