The range of antiferromagnetic coupling governs the conductivity: semiconducting behavior and ammonia gas sensing property of diamagnetic hexaradical-containing tetranuclear CoIII4 cluster and its nonradical congener,Chemical Communications

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The range of antiferromagnetic coupling governs the conductivity: semiconducting behavior and ammonia gas sensing property of diamagnetic hexaradical-containing tetranuclear CoIII4 cluster and its nonradical congener
Chemical Communications ( IF 4.9 ) Pub Date : 2020-11-06 , DOI: 10.1039/d0cc04061d
Prasenjit Sarkar _{1,

2,

3,

4} , Tukhar Jyoti Konch _{1,

2,

3,

4} , Tapas Kamilya _{4,

5,

6,

7} , Kalyan Raidongia _{1,

2,

3,

4} , Somobrata Acharya _{4,

5,

6,

7} , Chandan Mukherjee _{1,

2,

3,

4}

Affiliation

Long-range antiferromagnetic coupling impeded electron flow through the hexaradical-containing tetranuclear Co^III₄ complex (1), while the nonradical-containing tetranuclear Co^III₄ complex (2), with no paramagnetic centres, was a semiconductor and sensed NH₃ efficiently at room temperature (25 °C).

中文翻译：

反铁磁耦合的范围决定了电导率：含反磁性六价四核CoIII4团簇及其非自由基同类物的半导电行为和氨气感测特性

远距离反铁磁耦合阻止电子流过含六价基的四核Co ^III₄络合物（1），而无顺磁中心的无基量的四核Co ^III₄络合物（2）为半导体，在NH _3下有效地检测到NH ₃。室温（25°C）。

更新日期：2020-11-25

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