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Discussion on spectral, electrical and third-order nonlinear optical susceptibility of semi-organic tris(cyclohexylammonium) tris(o-chlorobenzoate) dihydrate single crystal
Journal of Materials Science: Materials in Electronics ( IF 2.8 ) Pub Date : 2020-11-24 , DOI: 10.1007/s10854-020-04729-1
M. Loganayaki , K. Senthil , S. Nandhini , A. Senthil , P. Murugakoothan , G. Vinitha

A semi-organic single crystal named tris(cyclohexylammonium) tris(o-chlorobenzoate) dihydrate (TCTCDH) had been successfully grown applying slow evaporation procedure. The developed crystal was involved for various characterization techniques. The structural property of the sample had been analyzed employing powder XRD study. The FT-IR spectral study was applied to confirm the existence of functional groups in the title compound. The optical property of the grown material has been explored using UV-visible NIR spectral study. The dielectric constant and dielectric loss were calculated to analyze the electrical property of the titular crystal. The third-order nonlinear susceptibility of the grown material was studied employing Z-scan technique using semiconductor laser at 532 nm. The thermal behavior of TCTCDH compound was ascertained using thermo-gravimetric analysis (TGA) and differential scanning calorimetry (DSC) analysis. The Vicker’s hardness study was employed to determine the mechanical stability of TCTCDH compound.



中文翻译:

半有机三(邻氯苯甲酸酯)二水合三(环己基铵)三晶体的光谱,电和三阶非线性光学敏感性的讨论

半有机单晶名为三(环己基铵)三(邻氯苯甲酸酯)二水合物(TCTCDH)已通过缓慢蒸发程序成功生长。所开发的晶体涉及各种表征技术。使用粉末XRD研究分析了样品的结构性质。FT-IR光谱研究用于确认标题化合物中官能团的存在。已使用紫外线可见近红外光谱研究探索了生长材料的光学特性。计算介电常数和介电损耗,以分析晶状晶体的电性能。使用Z扫描技术,使用半导体激光器在532 nm处研究了生长材料的三阶非线性磁化率。使用热重分析(TGA)和差示扫描量热法(DSC)分析确定TCTCDH化合物的热行为。使用维氏硬度研究确定TCTCDH化合物的机械稳定性。

更新日期:2020-11-25
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