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Chemistry of Metal Silicates and Germanates: The Largest Metal Polygermanate, K11Mn21Ge32O86(OH)9(H2O), with a 76 Å Periodic Lattice
Inorganic Chemistry ( IF 4.6 ) Pub Date : 2020-11-22 , DOI: 10.1021/acs.inorgchem.0c02303
Megan M. Smart 1 , Colin D. McMillen 1 , Kimberly Ivey 2 , Joseph W. Kolis 1
Affiliation  

An examination of manganese silicates and germanates revealed unusual structural motifs and extremely different chemistries, with identical hydrothermal reactions forming K2Mn2Si3O9 versus K11Mn21Ge32O86(OH)9(H2O). The germanate is exceptional in both its c-axis length (exceeding 76 Å) and unit cell volume (nearly 18000 Å3), the largest known polygermanate structure to our knowledge.

中文翻译:

金属硅酸盐和锗酸盐的化学性质:最大的金属多锗酸盐,K 11 Mn 21 Ge 32 O 86(OH)9(H 2 O),具有周期性的周期性晶格:76Å

对硅酸锰和锗酸锰的检查显示出不同寻常的结构图案和极为不同的化学性质,相同的水热反应形成K 2 Mn 2 Si 3 O 9与K 11 Mn 21 Ge 32 O 86(OH)9(H 2 O)。的锗是在它的两个特殊Ç轴长度(超过76埃)和晶胞体积(近18000埃3),最大已知聚锗结构就我们所知。
更新日期:2020-12-07
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