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Preparation of Pt/Al2O3 and PtPd/Al2O3 catalysts by supercritical deposition and their performance for oxidation of nitric oxide and propene
Catalysis Today ( IF 5.3 ) Pub Date : 2020-11-23 , DOI: 10.1016/j.cattod.2020.11.013
Hande Gunes 1 , Deniz Şanlı Yıldız 2 , Barkın Özener 2 , Gökhan Hisar 2 , Sarshad Rommel 3 , Mark Aindow 3 , Selmi Erim Bozbağ 1 , Can Erkey 1, 4
Affiliation  

Pt/Al2O3 and bimetallic PtPd/Al2O3 catalysts were prepared via supercritical deposition method using supercritical carbon dioxide. The effects of Pt loading of Pt/Al2O3 and Pd addition to Pt/Al2O3 on particle size, particle size distribution (PSD) and activity for NO and C3H6 oxidation and C3H6-selective catalytic reduction (C3H6-SCR) were investigated. Pt/Al2O3 catalysts were prepared with Pt loadings of 0.6, 1.2 and 2.1 wt% and a bimetallic PtPd/Al2O3 catalyst was prepared with total metal loading of 1.4 wt% and Pt:Pd molar ratio of 1.3:1. A small fraction of the particles agglomerated after calcination at 550 °C. Around 98 % of the particles had an average particle size of ∼1 nm. The rest of the particles were larger and average size of these larger particles was ∼10 nm for monometallic catalysts and ∼6.5 nm for PtPd/Al2O3. All catalysts were found to be active for NO and C3H6 oxidation and C3H6-SCR reactions. NO oxidation performance of 1.2 wt% Pt/Al2O3 catalyst was the highest. C3H6 oxidation activity increased with increasing metal content. Light-off temperature for C3H6 oxidation shifted to higher temperature in the presence of NO, suggesting competitive oxidation of C3H6 and NO. Concentration profiles indicated that C3H6-SCR started when C3H6 conversion by oxidation reached 50 %; C3H6 was consumed both by oxidation and C3H6-SCR at higher conversions.



中文翻译:

超临界沉积法制备Pt/Al2O3和PtPd/Al2O3催化剂及其对一氧化氮和丙烯的氧化性能

Pt/Al 2 O 3和双金属PtPd/Al 2 O 3催化剂采用超临界二氧化碳通过超临界沉积法制备。Pt负载Pt/Al 2 O 3和Pd添加到Pt/Al 2 O 3对粒度、粒度分布(PSD)和NO和C 3 H 6氧化和C 3 H 6选择性催化活性的影响研究了还原(C 3 H 6 -SCR)。铂/铝2 O 3制备了 Pt 负载量为 0.6、1.2 和 2.1 wt% 的催化剂,制备了总金属负载量为 1.4 wt% 和 Pt:Pd 摩尔比为 1.3:1的双金属 PtPd/Al 2 O 3催化剂。一小部分颗粒在 550 °C 煅烧后发生团聚。大约 98% 的颗粒具有约 1 nm 的平均粒径。其余颗粒较大,对于单金属催化剂,这些较大颗粒的平均尺寸约为 10 nm,对于 PtPd/Al 2 O 3约为 6.5 nm 。发现所有催化剂对NO和C 3 H 6氧化以及C 3 H 6 -SCR反应都是有活性的。1.2 wt% Pt/Al 2 O的NO氧化性能3催化剂最高。C 3 H 6氧化活性随着金属含量的增加而增加。在 NO 存在下,C 3 H 6氧化的起燃温度转移到更高的温度,表明 C 3 H 6和 NO的竞争性氧化。浓度曲线表明,当 C 3 H 6氧化转化率达到 50%时,C 3 H 6 -SCR 开始;C 3 H 6在较高转化率下被氧化和C 3 H 6 -SCR 消耗。

更新日期:2020-11-23
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