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Defective molybdenum disulfide nanosheet for elemental mercury capture in simulated flue gas
Journal of the Energy Institute ( IF 5.7 ) Pub Date : 2020-11-21 , DOI: 10.1016/j.joei.2020.11.007
Lingtao Yang , Jiang Wu , Bin Li , Dongjing Liu

Two-dimensional transition-metal dichalcogenides have gained increasing concerns because of their distinct structural features and also display great potential in mercury removal. Herein, a defect-rich MoS2 nanosheet is synthesized by using hydrothermal method and applied for adsorptive capture of elemental mercury (Hg0) in simulated flue gas at low temperature. It exhibits excellent Hg0 removal performance due to its ultra-thin lamellar and defective structures with ample exposed adsorption sites. The Hg0 removal efficiency of the defective MoS2 nanosheet is all above 93% when the reaction temperature is within 25–150 °C. Besides, presence of NO has no influence on Hg0 removal, while SO2 subtly reduces the Hg0 removal efficiency due to competitive adsorption. Mo4+, S2−, and S22− ions take part in the Hg0 removal process, which transfers Hg0 into Mo–Hg amalgam and HgS. The process of Hg0 adsorption on the defective MoS2 nanosheet obeys the pseudo-first-order and pseudo-second-order kinetic model.



中文翻译:

缺陷二硫化钼纳米片用于模拟烟气中元素汞的捕集

二维过渡金属二卤化物因其独特的结构特征而引起越来越多的关注,并且在除汞方面也显示出巨大的潜力。在此,富缺陷-MOS 2纳米片是通过使用水热法合成并申请了元素汞的吸附捕获(汞柱0模拟的烟道气中在低温下)。由于其超薄的层状结构和具有充足暴露位置的不良结构,它具有出色的Hg 0去除性能。当反应温度在25–150°C范围内时,有缺陷的MoS 2纳米片的Hg 0去除效率均高于93%。此外,NO的存在对Hg 0没有影响SO 2会由于竞争性吸附而巧妙地降低Hg 0的去除效率。Mo 4+,S 2−和S 2 2-离子参与Hg 0的去除过程,该过程将Hg 0转移到Mo–Hg汞齐和HgS中。Hg 0在有缺陷的MoS 2纳米片上的吸附过程遵循伪一级和伪二级动力学模型。

更新日期:2020-11-27
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