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Polyoxometalate-based hydrogen-bonded organic frameworks as a new class of proton conducting materials
CrystEngComm ( IF 3.1 ) Pub Date : 2020-11-10 , DOI: 10.1039/d0ce01578d
Ning-Ning Ji 1, 2, 3, 4 , Zhi-Qiang Shi 1, 2, 3, 4 , Xiao-Xin Xie 4, 5, 6, 7 , Gang Li 4, 5, 6, 7
Affiliation  

To develop new types of crystalline proton conducting materials for fuel cells, a polyoxometalate-based hydrogen-bonded organic framework (PHOF) based on Keggin-type [PMo12O40]3− and phenylimidazole (PHOF 1) has been prepared. AC impedance analysis shows that the highest proton conductivity of PHOF 1 reaches up to 2.02 × 10−4 S cm−1 (100 °C, 98% RH).

中文翻译:

基于多金属氧酸盐的氢键有机骨架作为新型的质子传导材料

为了开发用于燃料电池的新型晶体质子传导材料,已经制备了基于Keggin型[PMo 12 O 40 ] 3-和苯基咪唑(PHOF 1)的基于多金属氧酸盐的氢键有机骨架(PHOF)。交流阻抗分析表明,PHOF 1的最高质子传导率达到2.02×10 -4 S cm -1(100°C,98%RH)。
更新日期:2020-11-21
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