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P(III)‐Mediated Cascade C‐N/C‐S Bond Formation: A Protocol towards the Synthesis of N,S‐Heterocycles and Spiro Compounds
Advanced Synthesis & Catalysis ( IF 5.4 ) Pub Date : 2020-11-20 , DOI: 10.1002/adsc.202001149
Saibabu Polina 1 , V. P. Rama Kishore Putta 1 , Raghuram Gujjarappa 2 , Virender Singh 3 , Prasad Pralhad Pujar 1 , Chandi C. Malakar 2
Affiliation  

A P(III)‐mediated entry towards construction of C−N/C−S bond has been devised. The developed heterocyclization method was exercised for the synthesis of a diverse range of N,S‐heterocycles and related spiro molecules. P(NMe2)3 revealed the maximum efficacies under the aerobic reaction conditions and a spectrum of bis‐nucleophiles, and isothiocyanates were tolerated well to serve the access of manifold immense molecules.

中文翻译:

P(III)介导的级联C-N / C-S键形成:合成N,S-杂环和螺化合物的协议

已经设计了AP(III)介导的C-N / C-S键的构建方法。运用发达的杂环化方法合成了各种NS杂环和相关螺环分子。P(NMe 23显示了在有氧反应条件下和双亲核试剂谱中的最大效率,并且异硫氰酸酯具有良好的耐受性,可用于吸收大量巨大的分子。
更新日期:2021-01-19
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