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Carbon@NiCoO 2 -CoOOH Double-Shelled Hollow Burr Nanospheres as Anode Material for Lithium-Ion Batteries
Journal of Electronic Materials ( IF 2.1 ) Pub Date : 2020-11-19 , DOI: 10.1007/s11664-020-08600-1
Qiuhe Yang , Yongfeng Yuan , Qiang Chen

With SiO2 spheres as the template and PPy as carbon precursor, a layer of amorphous carbon has been tightly coated on NiCoO2-CoOOH hollow burr nanospheres, forming a unique double-shelled hollow burr nanospheres structure. Carbon@NiCoO2-CoOOH presents a high discharge capacity (1334 mAh g−1 at a current density of 100 mA g−1), a stable cycling performance (912 mAh g−1 at the 600th cycle at 200 mA g−1), and a desirable rate capability when used as anode material for lithium-ion batteries. The outstanding electrochemical performance results from the synergy effect of the hollow burr nanosphere and the amorphous carbon shell. The hollow burr nanosphere endows NiCoO2 and CoOOH with a high electrochemical activity and a good accommodation capability to volume change. The amorphous carbon shell remarkably reinforces the structure stability and electronic conductivity of NiCoO2 and CoOOH.



中文翻译:

碳@NiCoO 2 -CoOOH双壳空心毛刺纳米球作为锂离子电池的负极材料

以SiO 2球为模板,PPy为碳前驱体,在NiCoO 2 -CoOOH中空毛刺纳米球上紧密包覆一层无定形碳,形成独特的双壳中空毛刺纳米球结构。碳@ NiCoO 2 -COOOH呈现高放电容量(毫安1334克-1在100mA g的电流密度-1),稳定的循环性能(912毫安克-1在第600循环以200mA克-1),以及用作锂离子电池负极材料时的理想倍率性能。优异的电化学性能来自空心毛刺纳米球和无定形碳壳的协同效应。中空的毛刺纳米球赋予NiCoO 2和CoOOH较高的电化学活性,并且对体积变化具有良好的适应能力。非晶碳壳显着增强了NiCoO 2和CoOOH的结构稳定性和电子导电性。

更新日期:2020-11-19
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