Hypervalent iodine-promoted dearomatization of phenols has received intense attention. This mini-review summarizes recent computational mechanistic studies of phenolic dearomatizations promoted by hypervalent iodine(III) reagents or catalysts. The first part of this review describes mechanisms of racemic dearomatization of phenols, paying special attention to the associative and dissociative pathways. The second part focuses on mechanisms and selectivities of diastereo- or enantio-selective dearomatization of phenols.

中文翻译：

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高价碘促进苯酚脱芳烃机理的最新计算研究

高价碘促进的苯酚脱芳香化受到了广泛关注。这份小型综述总结了由高价碘（III）试剂或催化剂促进的酚脱芳香化作用的最新计算机理研究。本文的第一部分描述了苯酚的消旋脱芳香化作用的机制，并特别注意了缔合和解离途径。第二部分着重于苯酚的非对映或对映选择性脱芳构作用的机理和选择性。