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Gel-Casting Prepared Porous Si 3 N 4 Ceramics with Different Contents of Y 2 O 3 and Al 2 O 3 Additives
Journal of Materials Engineering and Performance ( IF 2.3 ) Pub Date : 2020-11-18 , DOI: 10.1007/s11665-020-05314-7
Chunrong Zou , Shaojun Guo , Xiaosong Zhou , Song Li , Chunlei Yan , Tongsheng Shen

Porous Si3N4 ceramics were prepared via a controlled gel-casting process followed by gas pressure sintering with 8 wt.% Y2O3 and Al2O3 additives. The gel-casting parameters including slurry pH value, AM: MBAM ratio, degassing procedure, drying condition and decarbonize process were optimized, and the effects of different Y2O3: Al2O3 ratios on the microstructure and properties of the Si3N4 ceramics were investigated. With an optimized gel-casting process, a high solid loading of 46.5 vol.% was achieved, and as the Y2O3 content decreased from 6 to 1 wt.%, the porosity of Si3N4 ceramics declined from 36.3 to 27.5% while the β-Si3N4 phase content reduced from 38.9 to 15.0%. The bending strength and elastic modulus of the ceramics varied with different Y2O3: Al2O3 ratios and were influenced by the porosity as well as the tailored interlocking structure of elongated β-Si3N4 grains. The Si3N4 ceramics also exhibited low and stable dielectric constants.



中文翻译:

Y 2 O 3和Al 2 O 3添加剂含量不同的凝胶铸造多孔Si 3 N 4陶瓷

多孔Si 3 N 4陶瓷是通过受控的凝胶浇铸工艺制备的,然后用8 wt%的Y 2 O 3和Al 2 O 3添加剂进行气压烧结。优化了浆料的pH值,AM:MBAM比,脱气步骤,干燥条件和脱碳工艺等凝胶浇铸参数,不同的Y 2 O 3:Al 2 O 3比对Si 3的微观结构和性能的影响。研究了N 4陶瓷。通过优化的凝胶浇铸工艺,获得了46.5 vol。%的高固含量,而Y 2ø 3含量降低为6〜1重量%,Si的孔隙率3 Ñ 4陶瓷从36.3下降到27.5%,而β型Si 3 Ñ 4相含量降低从38.9%至15.0%。的弯曲强度和陶瓷的弹性模量不同的变化Ý 2 ö 3:AL 2 ö 3比和由孔隙率以及细长β-Si的定制互锁结构被影响3个Ñ 4晶粒。Si 3 N 4陶瓷还表现出低而稳定的介电常数。

更新日期:2020-11-18
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