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Solvothermal Preparation of Luminescent Zinc(II) and Cadmium(II) Coordination Complexes Based On the New Bi-Functional Building Block and Photo-Luminescent Sensing For Cu2+, Al3+ And L-Lysine
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy ( IF 4.4 ) Pub Date : 2020-11-17 , DOI: 10.1016/j.saa.2020.119214
Yang Fan Shi , Yu Peng Jiang , Ping Ping Sun , Kuo Wang , Zi Qing Zhang , Na Jia Zhu , Rui Guo , Yi Yun Zhang , Xing Ze Wang , Yuan Yuan Liu , Jian Zhong Huo , Xin Rui Wang , Bin Ding

In industry, over usage of Cu2+ and Al3+ will lead to toxic wastewater, which further to give serious pollution for the environment. On the other hand, L-lysine can enhance serotonin release in the amygdala, with subsequent changes in psychobehavioral responses to stress. Therefore it is the urgent problem to design a method for detecting the amount of Cu2+, Al3+, and L-lysine. In this work, through the solvothermal synthesis method, two new coordination complexes based on the new bifunctional building block 4'-(1H-1,2,4-triazole-1-yl)- [1,1'-biphenyl]-4-carboxylic acid (HL) have been synthesized, namely, [Zn(L)2·4H2O] (complex 1) and [Cd(L)2·4H2O] (complex 2). X-ray single-crystal diffractometer was used to analyze its structure, powder X-ray diffraction (PXRD) patterns confirmed that 1 and 2 powder’s purity and 1 can keep stable during the detection process of Cu2+, Al3+, and L-lysine, respectively. Elemental analysis, thermogravimetric analysis, infrared analysis, ultraviolet analysis and fluorescent spectrum have been used to characterize these complexes. The photo-luminescent test showed that 1 can accurately recognize Al3+ and Cu2+ among various cations. On the other hand, 1 can distinguish L-lysine among amino acid molecules. Therefore, 1 can be utilized as a multifunctional fluorescent probe for Al3+(Ksv = 1.5570×104 [M]−1), Cu2+(Ksv = 1.4948×104 [M]−1) and L-lysine (Ksv = 4.9118×104 [M]−1) with low detection limits (17.5 μM, 18.2 μM, 5.6 μM) respectively.



中文翻译:

基于新型双功能基团和​​Cu 2 +,Al 3+和L-赖氨酸的光致发光传感的溶剂热制备发光的锌(II)和镉(II)配合物

在工业上,Cu 2+和Al 3+的过量使用会产生有毒废水,进一步给环境造成严重污染。另一方面,L-赖氨酸可增强杏仁核中5-羟色胺的释放,并随之改变心理行为对压力的反应。因此,设计一种检测Cu 2 +,Al 3+和L-赖氨酸含量的方法是当务之急。在这项工作中,通过溶剂热合成方法,基于新的双功能结构单元4'-(1H-1,2,4-三唑-1-基)-[1,1'-联苯] -4的两个新的配位化合物-羧酸(HL),即[Zn(L)2 ·4H 2 O](配合物1)和[Cd(L)2·4H 2 O](络合物2)。用X射线单晶衍射仪分析了其结构,粉末X射线衍射图(PXRD)证实了12粉末的纯度和1在Cu 2 +,Al 3+和L的检测过程中保持稳定。-赖氨酸。元素分析,热重分析,红外分析,紫外分析和荧光光谱已用于表征这些配合物。光致发光测试表明1可以准确识别各种阳离子中的Al 3+和Cu 2+。另一方面,1可以区分氨基酸分子之间的L-赖氨酸。因此,可以将1用作Al 3+(K sv = 1.5570×10 4 [M] -1),Cu 2+(K sv = 1.4948×10 4 [M] -1)和L-的多功能荧光探针。赖氨酸(K sv = 4.9118×10 4 [M] -1)分别具有低检测限(17.5μM,18.2μM,5.6μM )。

更新日期:2020-11-17
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