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Effects of Cl − and AC on the Corrosion Behavior of 2507 Super Duplex Stainless Steel in a Simulated Concrete Pore Solution
Journal of Materials Engineering and Performance ( IF 2.3 ) Pub Date : 2020-11-17 , DOI: 10.1007/s11665-020-05302-x
M. Zhu , Q. Zhang , Y. F. Yuan , S. Y. Guo , J. Pan

The effects of Cl concentration and applied alternating current (AC) on the corrosion behavior of 2507 super duplex stainless steel (SDSS) were studied in a saturated Ca(OH)2 solution by electrochemical measurements, immersion test, and x-ray photoelectron spectroscopy. The results show that the presence of Cl ions accelerates the corrosion of 2507 SDSS in the saturated Ca(OH)2 solution. The protective ability of passive film decreases as Cl concentration increases, especially at the concentration of 10% Cl. As the applied iAC increases, the ip value increases, and the Ep value decreases. The applied AC increases the number of defects within the passive film, affects the electronic property of the surface film, which results in a harmful effect on the passive film, and weakens its anti-corrosion property. The higher the iAC, the more severe the damage influence is. Moreover, imposed AC promotes the pitting corrosion sensitivity of SDSS and enhances its corrosion rate. The applied AC and the addition of Cl exert a combined effect, reducing the corrosion resistance of passive film formed on 2507 SDSS.



中文翻译:

Cl-和AC对2507超级双相不锈钢在模拟混凝土孔隙溶液中腐蚀行为的影响

氯的效果-浓度和施加的交变电流(AC)上(SDSS)的2507超级双相不锈钢的腐蚀行为在饱和的Ca(OH)进行了研究2溶液通过电化学测量,浸渍试验,和x射线光电子能谱法。结果表明,氯的存在-离子加速2507 SDSS的在饱和的Ca(OH)腐蚀2溶液。钝化膜的保护能力降低例如Cl -浓度的增加,特别是在10%的Cl的浓度- 。随着施加的i AC的增加,i p值增加,而E p值降低。施加的交流电会增加钝化膜中的缺陷数量,影响表面膜的电子性能,从而对钝化膜产生有害影响,并削弱其抗腐蚀性能。i AC越高,损坏影响就越严重。此外,强加的交流促进了SDSS的点蚀敏感性,并提高了其腐蚀速率。所施加的AC和加法的Cl -施加的组合效果,减少形成于2507 SDSS钝化膜的耐腐蚀性。

更新日期:2020-11-17
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