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Study of reaction mechanism, structural, optical and oxygen vacancy-controlled luminescence properties of Eu-modified Sr2SnO4 Ruddlesden popper oxide
Physica B: Condensed Matter ( IF 2.8 ) Pub Date : 2020-11-16 , DOI: 10.1016/j.physb.2020.412708
Upendra Kumar , Shail Upadhyay , Parvez Ahmad Alvi

Eu-doped Sr2SnO4 samples were synthesized using conventional ceramic route, followed by calcination at 1000 °C. Rietveld refinement analysis of XRD data indicates that the samples are single phase and crystallized into tetragonal crystal structure. Functional groups and metal-oxygen interaction has been studied using FTIR spectroscopy. The XPS analysis revealed the presence of oxygen vacancy, Sr in Sr2+ and Sn in Sn2+/Sn4+ in sample. The PL spectrum shows five peaks of Eu3+ due to transition 5D07F0,1,2,3,4. The transition peaks 5D07F0 and 5D07F2 found most intense in PL spectra, and their ratio with 5D07F1 were increased up to SSE6 and then decreased for SSE10, due to quenching phenomenon. An efficient energy transfer from oxygen vacancy to 5D07F0 state leads to enormously increase in their intensity. By utilizing these absorption states and emission states as metastable state, the present sample can be used in UV-filter, UV-detector, and optical device applications.



中文翻译:

Eu修饰的Sr 2 SnO 4 Ruddlesden Popper氧化物的反应机理,结构,光学和氧空位控制的发光性质的研究

使用常规陶瓷路线合成Eu掺杂的Sr 2 SnO 4样品,然后在1000°C下煅烧。XRD数据的Rietveld细化分析表明,样品为单相且结晶为四方晶体结构。使用FTIR光谱研究了官能团和金属-氧相互作用。XPS分析显示样品中存在氧空位,Sr 2+中的Sr和Sn 2+ / Sn 4+中的Sn 。由于跃迁5 D 07 F 0,1,2,3,4,PL谱显示出Eu 3+的五个峰。过渡峰5 D 0在PL光谱中发现→ 7 F 05 D 07 F 2最强,由于淬灭现象,它们与5 D 07 F 1的比率增加到SSE6,然后降低到SSE10。从氧空位到5 D 07 F 0状态的有效能量转移导致其强度大大增加。通过利用这些吸收状态和发射状态作为亚稳态,本样品可以用于紫外线滤光片,紫外线检测器和光学装置应用中。

更新日期:2021-01-18
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