Physica B: Condensed Matter ( IF 2.8 ) Pub Date : 2020-11-16 , DOI: 10.1016/j.physb.2020.412708 Upendra Kumar , Shail Upadhyay , Parvez Ahmad Alvi
Eu-doped Sr2SnO4 samples were synthesized using conventional ceramic route, followed by calcination at 1000 °C. Rietveld refinement analysis of XRD data indicates that the samples are single phase and crystallized into tetragonal crystal structure. Functional groups and metal-oxygen interaction has been studied using FTIR spectroscopy. The XPS analysis revealed the presence of oxygen vacancy, Sr in Sr2+ and Sn in Sn2+/Sn4+ in sample. The PL spectrum shows five peaks of Eu3+ due to transition 5D0→7F0,1,2,3,4. The transition peaks 5D0→7F0 and 5D0→7F2 found most intense in PL spectra, and their ratio with 5D0→7F1 were increased up to SSE6 and then decreased for SSE10, due to quenching phenomenon. An efficient energy transfer from oxygen vacancy to 5D0→7F0 state leads to enormously increase in their intensity. By utilizing these absorption states and emission states as metastable state, the present sample can be used in UV-filter, UV-detector, and optical device applications.
中文翻译:
Eu修饰的Sr 2 SnO 4 Ruddlesden Popper氧化物的反应机理,结构,光学和氧空位控制的发光性质的研究
使用常规陶瓷路线合成Eu掺杂的Sr 2 SnO 4样品,然后在1000°C下煅烧。XRD数据的Rietveld细化分析表明,样品为单相且结晶为四方晶体结构。使用FTIR光谱研究了官能团和金属-氧相互作用。XPS分析显示样品中存在氧空位,Sr 2+中的Sr和Sn 2+ / Sn 4+中的Sn 。由于跃迁5 D 0 → 7 F 0,1,2,3,4,PL谱显示出Eu 3+的五个峰。过渡峰5 D 0在PL光谱中发现→ 7 F 0和5 D 0 → 7 F 2最强,由于淬灭现象,它们与5 D 0 → 7 F 1的比率增加到SSE6,然后降低到SSE10。从氧空位到5 D 0 → 7 F 0状态的有效能量转移导致其强度大大增加。通过利用这些吸收状态和发射状态作为亚稳态,本样品可以用于紫外线滤光片,紫外线检测器和光学装置应用中。