Catalyst-free, visible-light-promoted S–H insertion reaction between thiols and α-diazoesters,Organic & Biomolecular Chemistry

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Catalyst-free, visible-light-promoted S–H insertion reaction between thiols and α-diazoesters
Organic & Biomolecular Chemistry ( IF 3.2 ) Pub Date : 2020-11-06 , DOI: 10.1039/d0ob02006k
Jingya Yang _{1,

2,

3,

4} , Ganggang Wang _{1,

2,

3,

4} , Shuwen Chen _{1,

2,

3,

4} , Ben Ma _{1,

2,

3,

4} , Hongyan Zhou _{1,

2,

3,

4,

5} , Menghui Song _{1,

2,

3,

4} , Cai Liu _{1,

2,

3,

4} , Congde Huo _{1,

2,

3,

4}

Affiliation

A visible-light-promoted S–H insertion reaction between thiols and α-diazoesters was developed. The reaction proceeded smoothly at room temperature with a broad substrate scope, affording various thioethers in moderate to excellent yields. The catalyst- and additive-free nature, sustainable energy source and mild reaction conditions make this strategy more eco-friendly.

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