Synthesis of carboxylic acids and derivatives using CO₂ as a sustainable and renewable source of carboxyl is most probably the area that has experienced the most growth in the field of CO₂ conversion reactions. Over the years, an enormous effort has been put forth by scientists toward exploration of the utility of various nucleophilic partners in the coupling with electrophilic CO₂. Organosilicon compounds are one of the latest nucleophilic reagents that was joined to the story of carboxylation reactions with CO₂ and has been the subject of a number of studies in recent years. The aim of this review is to present an overview of the recent advances and achievements of the desilylative carboxylation of organosilicon compounds, with particular emphasis on the mechanistic aspects of the reactions.

使用CO ₂作为可持续和可再生的羧基来源的羧酸及其衍生物的合成很可能是在CO ₂转化反应领域中增长最快的领域。多年来，科学家们为探索各种亲核伴侣在与亲电子CO ₂偶联中的效用进行了巨大的努力。有机硅化合物是最新的亲核试剂之一，与CO ₂的羧化反应有关并且近年来已经成为许多研究的主题。这篇综述的目的是概述有机硅化合物的脱甲硅烷基化羧化反应的最新进展和成就，特别着重于反应的机理方面。