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Sputter-Grown Pd-Capped CuO Thin Films for a Highly Sensitive and Selective Hydrogen Gas Sensor
Journal of Electronic Materials ( IF 2.1 ) Pub Date : 2020-11-10 , DOI: 10.1007/s11664-020-08588-8
Prashant Yadav , Ashwani Kumar , Amit Sanger , Yogendra K. Gautam , Beer Pal Singh

In the present work, hydrogen gas sensing properties of palladium-capped copper oxide (Pd/CuO) thin films have been investigated. The Pd/CuO thin films were deposited on glass substrate for different deposition times (10–30 min) using direct current magnetron sputtering. The Pd/CuO thin films were characterized by x-ray diffraction, field emission scanning electron microscopy, atomic force microscopy and x-ray photoelectron spectroscopy for their structural, morphological and compositional properties, respectively. The Pd/CuO thin film sensor deposited for 10 min presents a remarkable sensing performance with fast response/recovery time of 10 s/50 s for hydrogen gas at a concentration of (1000 ppm) and optimum operating temperature of 300°C. The sensor is observed to be highly selective towards hydrogen (H2) gas compared to the other gases such as carbon monoxide (CO) and ammonia (NH3). The sensor is stable under high humidity conditions (60% RH). The studied Pd/CuO thin film sensor can be used to design a simple and low-cost sensor to detect low concentrations of H2 gas for use in hydrogen-driven industries.



中文翻译:

溅射生长的Pd包覆的CuO薄膜,用于高灵敏度和选择性的氢气传感器

在目前的工作中,已经研究了钯盖的氧化铜(Pd / CuO)薄膜的氢气感测特性。使用直流磁控溅射将Pd / CuO薄膜以不同的沉积时间(10–30分钟)沉积在玻璃基板上。通过X射线衍射,场发射扫描电子显微镜,原子力显微镜和X射线光电子能谱分别对Pd / CuO薄膜的结构,形态和组成特性进行了表征。沉积10分钟的Pd / CuO薄膜传感器具有卓越的感测性能,对于浓度为(1000 ppm)的氢气和300°C的最佳工作温度,响应/恢复时间为10 s / 50 s。观察到该传感器对氢(H 2)气体与其他气体(例如一氧化碳(CO)和氨(NH 3))相比。该传感器在高湿度条件(60%RH)下稳定。所研究的Pd / CuO薄膜传感器可用于设计一种简单且低成本的传感器,以检测氢驱动行业中使用的低浓度H 2气体。

更新日期:2020-11-12
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