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Effects of Bi3+ on down-/up-conversion luminescence, temperature sensing and optical transition properties of Bi3+/Er3+ co-doped YNbO4 phosphors
Journal of Rare Earths ( IF 4.9 ) Pub Date : 2020-11-07 , DOI: 10.1016/j.jre.2020.11.001
Xin Wang 1 , Xiangping Li 1 , Hongquan Yu 1 , Sai Xu 1 , Jiashi Sun 1 , Lihong Cheng 1 , Xizhen Zhang 1 , Jinsu Zhang 1 , Yongze Cao 1 , Baojiu Chen 1
Affiliation  

A series of YNbO4:Bi3+ and YNbO4:Bi3+/Er3+ phosphors were prepared by a conventional high temperature solid–state reaction method. The results of XRD and Rietveld refinement confirm that monoclinic phase YNbO4 samples are achieved. The down-/up-conversion luminescence of Er3+ ions was investigated under the excitation of ultraviolet light (327 nm) and near infrared light (980 nm). Under 327 nm excitation, broad visible emission band from Bi3+ ions and characteristic green emission peaks from Er3+ ions are simultaneously observed, while only strong green emissions from Er3+ ions are detected upon excitation of 980 nm. Remarkable emission enhancement is observed in down-/up-conversion luminescence processes by introducing Bi3+ ions into Er3+-doped YNbO4 phosphors. Pumped current versus up-conversion emission intensity study shows that two-photon processes are responsible for both the green and the red up-conversion emissions of Er3+ ion. Through the study of the temperature sensing property of Er3+ ion, it is affirmed that the temperature sensitivity is sensitive to the doping concentration of Bi3+ ions. By comparing the experimental values of the radiative transition rate ratio of the two green emission levels of Er3+ ions and the theoretical values calculated by Judd-Ofelt (J-O) theory, it is concluded that the temperature sensing property of Er3+ ions is greatly affected by the energy level splitting.



中文翻译:

Bi3+ 对 Bi3+/Er3+ 共掺杂 YNbO4 荧光粉的下/上转换发光、温度传感和光学跃迁特性的影响

通过常规高温固相反应法制备了一系列YNbO 4 :Bi 3+和YNbO 4 :Bi 3+ /Er 3+荧光粉。XRD 和Rietveld 精修结果证实获得了单斜晶相YNbO 4样品。在紫外光(327 nm)和近红外光(980 nm)的激发下研究了Er 3+离子的下/上转换发光。在 327 nm 激发下,同时观察到来自 Bi 3+离子的宽可见发射带和来自 Er 3+离子的特征绿色发射峰,而来自 Er 3+的只有强绿色发射在 980 nm 的激发下检测离子。通过将Bi 3+离子引入Er 3+掺杂的YNbO 4荧光粉,在下/上转换发光过程中观察到显着的发射增强。泵浦电流与上转换发射强度的研究表明,双光子过程负责 Er 3+离子的绿色和红色上转换发射。通过对Er 3+离子的温度传感特性的研究,肯定了温度敏感性对Bi 3+离子的掺杂浓度敏感。通过比较 Er 3+两个绿色发射能级的辐射跃迁率比的实验值离子和Judd-Ofelt(JO)理论计算的理论值,得出Er 3+离子的温度传感特性受能级分裂的影响很大。

更新日期:2020-11-07
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