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Enhanced dielectric, ferroelectric, and optical properties in rare earth elements doped PMN-PT thin films
Journal of Advanced Ceramics ( IF 16.9 ) Pub Date : 2020-11-05 , DOI: 10.1007/s40145-020-0423-4
Shun Zhou , Dabin Lin , Yongming Su , Lin Zhang , Weiguo Liu

Rare earth (RE = La3+, Sm3+, Pr3+) ion doped Pb(Mg1/3Nb2/3)O3-PbTiO3 (RE-PMN-PT) ferroelectric thin films with compositions near the morphotropic phase boundary were grown on the Pt/TiO2/SiO2/Si(100) substrate using sol-gel/spin coating method. The phase structure, electrical properties, and photoluminescence performance of thin films were investigated systematically. The highly (100)-preferred orientation was obtained in pure perovskite Sm-PMN-0.30PT thin films with an average grain size of 131 nm. After 2.5% Sm3+ doping, the PMN-0.30PT thin films exhibited a triple enhancement of dielectric permittivity with a maximum value of 3500 at 1 kHz, a low dielectric loss of 1.3%, and high remanent polarization of 17.5 μC/cm2 at room temperature. In visible light and near-infrared band, the transmittance rate increased with PT content and showed the highest value of 85% in 2.5%Sm-PMN-0.31PT. In addition, the films presented strong red-orange emission at 599 nm, which was sensitively in temperature range of 248–273 K corresponding to the rhombohedral to monoclinic phase transition temperature.



中文翻译:

掺杂稀土元素的PMN-PT薄膜具有增强的介电,铁电和光学特性

稀土(RE = La 3+,Sm 3+,Pr 3+)离子掺杂的Pb(Mg 1/3 Nb 2/3)O 3 -PbTiO 3(RE-PMN-PT)铁电薄膜使用溶胶-凝胶/旋涂法在Pt / TiO 2 / SiO 2 / Si(100)衬底上生长相界。系统地研究了薄膜的相结构,电性能和光致发光性能。在平均晶粒尺寸为131 nm的纯钙钛矿Sm-PMN-0.30PT薄膜中获得了高度(100)优先的取向。2.5%Sm后3+掺杂后,PMN-0.30PT薄膜的介电常数提高了三倍,在1 kHz时最大值达到3500,在室温下介电损耗低至1.3%,剩余极化率高,达到了17.5μC/ cm 2。在可见光和近红外波段,透射率随PT含量的增加而增加,在2.5%Sm-PMN-0.31PT中显示最高值为85%。此外,这些薄膜在599 nm处呈现出强烈的红橙色发射,在248-273 K的温度范围内敏感,对应于菱形到单斜相的转变温度。

更新日期:2020-11-05
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