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Synthesis of Hydrobenzoimidazoles from para‐Quinamines and 1,3,5‐Triazinanes via a Formal [3+2] Annulation Reaction
Advanced Synthesis & Catalysis ( IF 5.4 ) Pub Date : 2020-11-03 , DOI: 10.1002/adsc.202001103
Xinping Zhang 1, 2 , Bin Cheng 1, 2 , Hui Li 1, 2 , Yixuan He 1, 2 , Wei Xu 1 , Xiaoguang Duan 2 , Haiyan Sun 1 , Taimin Wang 1 , Hongbin Zhai 1, 3
Affiliation  

The synthesis of hydrobenzoimidazoles from para‐quinamines and 1,3,5‐triazinanes was achieved via a formal [3+2] annulation reaction in the presence of In(OTf)3 as the catalyst. Further studies demonstrated that the synthesis of hydrobenzooxazoles could also be accomplished via the same strategy from para‐quinols and 1,3,5‐triazinanes.

中文翻译:

由对-奎宁胺和1,3,5-三嗪并通过正式的[3 + 2]环状反应合成氢苯并咪唑

在In(OTf)3作为催化剂的情况下,通过正式的[3 + 2]环化反应,由喹胺和1,3,5-三嗪酮合成氢化苯并咪唑。进一步的研究表明,也可以通过苯二酚和1,3,5-三嗪并酮的相同策略完成氢化苯并恶唑的合成。
更新日期:2020-11-03
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