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Nickel-Catalyzed α-1,3-Dienylation of 1,3-Dicarbonyl Compounds with Propargylic Carbonates
Synlett ( IF 2 ) Pub Date : 2020-10-05 , DOI: 10.1055/a-1282-9731
Naoki Ishida , Masahiro Murakami 1 , Yuka Kamino
Affiliation  

Herein reported is a nickel-catalyzed α-1,3-dienylation reaction of 1,3-dicarbonyl compounds with substituted propargylic (e.g., but-2-ynyl) carbonates. The propargyl unit changes into a 1,3-dienyl unit, which is incorporated at the α-position of the 1,3-dicarbonyl compounds.

中文翻译:

镍催化 1,3-二羰基化合物与炔丙碳酸酯的 α-1,3-二烯化

本文报道了镍催化的 1,3-二羰基化合物与取代的炔丙基(例如丁-2-炔基)碳酸酯的 α-1,3-二烯化反应。炔丙基单元变为 1,3-二烯基单元,其结合在 1,3-二羰基化合物的 α 位。
更新日期:2020-10-05
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