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Synthesis and structure of new 2,4-dicyano-6-oxo-3-phenylbicyclo[3.2.1]octane-2,4-dicarboxylates
Russian Chemical Bulletin ( IF 1.7 ) Pub Date : 2020-10-01 , DOI: 10.1007/s11172-020-2982-5
A. I. Ismiyev , V. V. Dotsenko , N. A. Aksenov , I. V. Aksenova , A. M. Magerramov

The sequential reaction of furfural with cyclic secondary amines and further with benzaldehyde and cyanoacetates affords new 2,4-dicyano-8-(R2N)-6-oxo-3-phenylbicyclo[3.2.1]-octane-2,4-dicarboxylates as rac-(1R,2R,3R,4S,5S,8R)-diastereomers. The structures of the reaction products were determined by X-ray diffraction.

中文翻译:

新型2,4-二氰基-6-氧代-3-苯基双环[3.2.1]辛烷-2,4-二羧酸酯的合成与结构

糠醛与环状仲胺以及进一步与苯甲醛和氰基乙酸酯的顺序反应得到新的 2,4-二氰基-8-(R2N)-6-氧代-3-苯基双环[3.2.1]-辛烷-2,4-二羧酸酯rac-(1R,2R,3R,4S,5S,8R)-非对映异构体。反应产物的结构由X射线衍射确定。
更新日期:2020-10-01
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