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Metal Halide Perovskite@Metal‐Organic Framework Hybrids: Synthesis, Design, Properties, and Applications
Small ( IF 13.3 ) Pub Date : 2020-10-30 , DOI: 10.1002/smll.202004891
Surendra K. Yadav 1 , G. Krishnamurthy Grandhi 2 , Deepak P. Dubal 3 , John C. Mello 1 , Michal Otyepka 4 , Radek Zbořil 4 , Roland A. Fischer 5 , Kolleboyina Jayaramulu 4, 6
Affiliation  

Metal halide perovskites (MHPs) have excellent optoelectronic and photovoltaic applications because of their cost‐effectiveness, tunable emission, high photoluminescence quantum yields, and excellent charge carrier properties. However, the potential applications of the entire MHP family are facing a major challenge arising from its weak resistance to moisture, polar solvents, temperature, and light exposure. A viable strategy to enhance the stability of MHPs could lie in their incorporation into a porous template. Metal‐organic frameworks (MOFs) have outstanding properties, with a unique network of ordered/functional pores, which render them promising for functioning as such a template, accommodating a wide range of MHPs to the nanosized region, alongside minimizing particle aggregation and enhancing the stability of the entrapped species. This review highlights recent advances in design strategies, synthesis, characterization, and properties of various hybrids of MOFs with MHPs. Particular attention is paid to a critical review of the emergence of MHP@MOF for comprehensive studies of next‐generation materials for various technological applications including sensors, photocatalysis, encryption/decryption, light‐emitting diodes, and solar cells. Finally, by summarizing the state‐of‐the‐art, some promising future applications of reported hybrids are proposed. Considering the inherent correlation and synergic functionalities of MHPs and MOFs, further advancement; new functional materials; and applications can be achieved through designing MHP@MOF hybrids.

中文翻译:

金属卤化物钙钛矿@金属-有机骨架混合物:合成,设计,性质和应用

金属卤化物钙钛矿(MHP)由于具有成本效益,可调谐发射,高光致发光量子产率和出色的电荷载流子特性而在光电和光伏领域具有出色的应用。但是,整个MHP系列的潜在应用面临着巨大的挑战,这是由于其对湿气,极性溶剂,温度和光线的抵抗力较弱。增强MHP稳定性的可行策略可能在于将其掺入多孔模板中。金属有机骨架(MOF)具有出色的性能,具有独特的有序/功能性孔网络,这使其有希望用作这样的模板,将各种MHP容纳在纳米区域,同时最大程度地减少颗粒聚集并增强纳米粒子的结构。被困物种的稳定性。这篇综述重点介绍了MOF与MHP的各种混合体在设计策略,合成,表征和特性方面的最新进展。特别关注对MHP @ MOF的出现进行的严格审查,以全面研究用于各种技术应用的下一代材料,包括传感器,光催化,加密/解密,发光二极管和太阳能电池。最后,通过总结最新技术,提出了已报道的混合动力汽车的一些有希望的未来应用。考虑到MHP和MOF的内在关联和协同功能,需要进一步发展;新功能材料;通过设计MHP @ MOF混合动力车可以实现应用。MOFs与MHPs的各种杂种的合成和性能 特别关注对MHP @ MOF的出现进行的严格审查,以全面研究用于各种技术应用的下一代材料,包括传感器,光催化,加密/解密,发光二极管和太阳能电池。最后,通过总结最新技术,提出了已报道的混合动力汽车的一些有希望的未来应用。考虑到MHP和MOF的内在关联和协同功能,需要进一步发展;新功能材料;通过设计MHP @ MOF混合动力车可以实现应用。MOFs与MHPs的各种杂种的合成和性能 特别关注对MHP @ MOF的出现进行的严格审查,以全面研究用于各种技术应用的下一代材料,包括传感器,光催化,加密/解密,发光二极管和太阳能电池。最后,通过总结最新技术,提出了已报道的混合动力汽车的一些有希望的未来应用。考虑到MHP和MOF的内在关联和协同功能,需要进一步发展;新功能材料;通过设计MHP @ MOF混合动力车可以实现应用。加密/解密,发光二极管和太阳能电池。最后,通过总结最新技术,提出了已报道的混合动力汽车的一些有希望的未来应用。考虑到MHP和MOF的内在关联和协同功能,需要进一步发展;新功能材料;通过设计MHP @ MOF混合动力车可以实现应用。加密/解密,发光二极管和太阳能电池。最后,通过总结最新技术,提出了已报道的混合动力汽车的一些有希望的未来应用。考虑到MHP和MOF的内在关联和协同功能,需要进一步发展;新功能材料;通过设计MHP @ MOF混合动力车可以实现应用。
更新日期:2020-11-27
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