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Evaluation of the ZrO2/Al2O3 system as catalysts in the catalytic transfer hydrogenation of furfural to obtain furfuryl alcohol
Applied Catalysis A: General ( IF 5.5 ) Pub Date : 2020-11-01 , DOI: 10.1016/j.apcata.2020.117905
C. García-Sancho , C.P. Jiménez-Gómez , N. Viar-Antuñano , J.A. Cecilia , R. Moreno-Tost , J.M. Mérida-Robles , J. Requies , P. Maireles-Torres

ZrO2, Al2O3 and ZrO2/Al2O3 with different Zr/Al molar ratio, have been synthesized by coprecipitation and subsequent calcination. The resulting catalysts were characterized by X-ray diffraction, transmission electron microscopy, N2 adsorption-desorption at -196 °C, CO2-thermoprogrammed desorption, NH3-thermoprogrammed desorption and X-ray photoelectron spectroscopy. Then, the catalysts were evaluated in the Meenwein-Ponndorf-Verley reduction of furfural (FUR) using 2-propanol as sacrificing alcohol. The catalyst with a Zr/Al molar ratio of 1, Zr5Al5, reached the highest conversion value at shorter reaction times, attaining a FUR conversion of 95 % with a yield of furfuryl alcohol (FOL) above 90 % after 5 h of reaction at 130 °C, due to its greater amount of acid sites, as well as higher specific surface area and pore volume.



中文翻译:

ZrO 2 / Al 2 O 3体系作为催化剂在糠醛催化转移加氢制糠醇中的评价

通过共沉淀和随后的煅烧合成了具有不同Zr / Al摩尔比的ZrO 2,Al 2 O 3和ZrO 2 / Al 2 O 3。通过X射线衍射,透射电子显微镜,-196℃下的N 2吸附-脱附,CO 2-热程序解吸,NH 3-热程序解吸和X射线光电子能谱表征所得催化剂。然后,使用2-丙醇作为牺牲醇,通过Meenwein-Ponndorf-Verley糠醛还原(FUR)评估催化剂。Zr / Al摩尔比为1,Zr 5 Al 5的催化剂在130°C下反应5小时后,在更短的反应时间内达到了最高的转化率值,FUR转化率达到95%,糠醇(FOL)的收率超过90%,原因是以及更高的比表面积和孔体积。

更新日期:2020-11-15
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