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Syntheses and structural characterization of manganese and cadmium coordination polymers constructed with bis(4-(1H-imidazol-1-yl)phenyl)methanone and dicarboxylate ligands
Zeitschrift für Naturforschung B ( IF 0.8 ) Pub Date : 2020-11-26 , DOI: 10.1515/znb-2020-0120
Gao-Feng Wang 1 , Shu-Wen Sun 1 , Hong Sun 1 , Bing-Wei Chang 1 , Jing Song 1 , Xia Yang 1
Affiliation  

Abstract Two coordination polymers (CPs), [Mn(bipmo)(pbtda)(H2O)] n (1), {[Cd(bipmo)(btda)]·2(H2O)]} n (2), (bipmo = bis(4-(1H-imidazol-1-yl)phenyl)methanone, H2pbtda = 2-phenylbutanedioic acid, H2btda = butanedioic acid), were synthesized by solvothermal methods. The products have been characterized by elemental analyses, IR spectroscopy, and single-crystal X-ray diffraction. The topological structure of 1 is based on 2-nodal nets with the Schläfli symbol {63}{69·8}, while that of 2 features a system with a sixfold penetration with the Schläfli symbol {66}.

中文翻译:

用双(4-(1H-咪唑-1-基)苯基)甲酮和二羧酸配体构建的锰和镉配位聚合物的合成和结构表征

摘要 两种配位聚合物 (CPs), [Mn(bipmo)(pbtda)(H2O)] n (1), {[Cd(bipmo)(btda)]·2(H2O)]} n (2), (bipmo =双(4-(1H-咪唑-1-基)苯基)甲酮,H2pbtda = 2-苯基丁二酸,H2btda = 丁二酸),通过溶剂热法合成。产品已通过元素分析、红外光谱和单晶 X 射线衍射进行了表征。1 的拓扑结构基于 Schläfli 符号 {63}{69·8} 的 2 节点网络,而 2 的拓扑结构基于 Schläfli 符号 {66} 的六重渗透系统。
更新日期:2020-11-26
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