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Simultaneously with large energy density and high efficiency achieved in NaNbO3-based relaxor ferroelectric ceramics
Journal of the European Ceramic Society ( IF 5.7 ) Pub Date : 2020-10-27 , DOI: 10.1016/j.jeurceramsoc.2020.10.049
Congcong Sun , Xiuli Chen , Junpeng Shi , Feihong Pang , Xiaoyan Dong , Hong yun Chen , Kangguo Wang , Xianjie Zhou , Huanfu Zhou

Dielectric capacitors are in urgent need of miniaturized and lightweight products. The new lead-free NaNbO3-based ferroelectric ceramic material is a good choice owing to its high energy storage density, superior charge/discharge performance and decent frequency/temperature stability. In this work, a novel lead-free relaxor ferroelectric ceramic, (1-x)NaNbO3-xBa(Mg1/3Nb2/3)O3 [(1-x)NN-xBMN, x = 0.18, 0.20, 0.22 and 0.24], was designed and prepared via a local random field strategy. The impedance analysis demonstrates that the introduction of BMN could enhance the insulation ability and breakdown strength of the (1-x)NN-xBMN ceramic. Finally, the excellent energy storage performances with simultaneously ultrahigh energy storage density (Wst~4.04 J/cm3), recoverable energy storage density (Wrec~3.51 J/cm3), efficiency (η~87 %) and fatigue endurance (number of cycles: 5000) are obtained in the 0.78NN-0.22BMN ceramic. In addition, excellent frequency (1~100 Hz) and temperature stability (20~140 °C) can also be observed in the 0.78NN-0.22BMN ceramic. It is crucial that the ceramic shows extremely short charge-discharge time (t0.9~45 ns), tremendous current density (CD~680 A/cm2), giant power density (PD~47.6 MW/cm3) and excellent temperature stability (30~150 °C). These results indicate that 0.78NN-0.22BMN ceramic is a promising dielectric capacitor material.



中文翻译:

同时在基于NaNbO 3的弛豫铁电陶瓷中实现高能量密度和高效率

介电电容器迫切需要小型化和轻量化的产品。新型无铅NaNbO 3基铁电陶瓷材料因其高的储能密度,出色的充电/放电性能以及良好的频率/温度稳定性而成为了不错的选择。在这项工作中,一种新型的无铅弛豫铁电陶瓷(1- x)NaNbO 3 - x Ba(Mg 1/3 Nb 2/3)O 3 [(1- x)NN- x BMN,x= 0.18、0.20、0.22和0.24]是通过局部随机场策略设计和制备的。阻抗分析表明,引入BMN可以增强(1- x)NN- x BMN陶瓷的绝缘能力和击穿强度。最后,优良的能量储存性能同时与超高能量存储密度(w ^ ST〜4.04焦耳/厘米3),可回收能量存储密度(w ^ REC〜3.51焦耳/厘米3),效率(η在0.78NN-0.22BMN陶瓷中获得了约87%的耐疲劳性(循环数:5000)。另外,在0.78NN-0.22BMN陶瓷中也可以观察到极好的频率(1〜100 Hz)和温度稳定性(20〜140°C)。至关重要的是,该陶瓷显示极短的充放电时间(0.9〜45纳秒),巨大电流密度(ç d〜680 A /厘米2),巨功率密度(P d〜47.6兆瓦/厘米3)和优异的温度稳定性(30〜150°C)。这些结果表明0.78NN-0.22BMN陶瓷是一种有前途的介电电容器材料。

更新日期:2020-12-01
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