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Multi-acrylate-based UV-curable dismantlable adhesives
International Journal of Adhesion and Adhesives ( IF 3.4 ) Pub Date : 2021-01-01 , DOI: 10.1016/j.ijadhadh.2020.102758
Hikaru Sugita , Keisuke Itou , Yoshikazu Itou , Natsuko Wada , Tomikazu Ueno Shin-ya Kurita , Youichi Hirose , Kazuki Hatase , Hitonari Matsumoto , Daigo Ichinohe

Abstract Herein, a dismantlable, photo-curable adhesive is reported. The adhesive is composed of a multi-acrylate oligomer with a tertiary ester, a photo radical initiator, a photo acid generator, and a phosphate-substituted acrylate as an adhesion promoter. Photo-exposure to the adhesive sandwiched between two glass slides induces crosslinking and causes the slides to bond to each other. Post-exposure baking promotes the acid-catalyzed decomposition of the hardened adhesive, which results in significantly decreased adhesion strength. An alkaline developer can easily remove the residual adhesive on the debonded glass plates, thus recovering glass transparency. Photo-bonding and debonding mechanisms were elucidated by spectroscopic analyses. By using the dismantlable adhesive, a small glass plate attached to a glass slide can be successfully transferred to another glass slide.

中文翻译:

多丙烯酸酯基紫外光固化可拆胶粘剂

摘要 本文报道了一种可拆卸、可光固化的粘合剂。该粘合剂由多丙烯酸酯低聚物与叔酯、光自由基引发剂、光酸产生剂和作为粘合促进剂的磷酸酯取代丙烯酸酯组成。对夹在两个载玻片之间的粘合剂进行曝光会引起交联并使载玻片彼此粘合。曝光后烘烤会促进固化后的粘合剂的酸催化分解,从而导致粘合强度显着降低。碱性显影剂可以很容易地去除脱粘玻璃板上残留的粘合剂,从而恢复玻璃的透明度。通过光谱分析阐明了光结合和脱粘机制。通过使用可拆卸的粘合剂,
更新日期:2021-01-01
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