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Influence of plasticizers on thermal and mechanical properties of biocomposite filaments made from lignin and polylactic acid for 3D printing
Composites Part B: Engineering ( IF 13.1 ) Pub Date : 2020-10-21 , DOI: 10.1016/j.compositesb.2020.108483
Sanjita Wasti , Eldon Triggs , Ramsis Farag , Maria Auad , Sushil Adhikari , Dilpreet Bajwa , Mi Li , Arthur J. Ragauskas

Polylactic acid (PLA) and organosolv lignin were mixed at different ratios and extruded to obtain PLA-lignin composite filaments. PLA was replaced with lignin up to 20 wt%. Two plasticizers (polyethylene glycol (PEG) 2000 and struktol TR451) were added in varying concentrations to enhance the properties of PLA_L20 (20% lignin in PLA) composite filaments. The effect of lignin in PLA, and PEG, and struktol in PLA_L20 composites was investigated via tensile test, differential scanning calorimetry, thermogravimetric analysis, scanning electron microscopy, Fourier transform infrared spectroscopy of the filaments, and dynamic mechanical analysis of 3D printed samples. A 2 wt% PEG was able to enhance both tensile stress and elongation at maximum load of PLA_L20 composite by 19% and 35%, respectively, whereas struktol TR451 was able to improve elongation at maximum load by 24%.



中文翻译:

增塑剂对木质素和聚乳酸制成的3D打印生物复合长丝热力学性能的影响

将聚乳酸(PLA)和有机溶剂木质素以不同比例混合并挤出以获得PLA-木质素复合长丝。PLA被木质素取代,含量最高为20 wt%。添加了不同浓度的两种增塑剂(聚乙二醇(PEG)2000和struktol TR451),以增强PLA_L20(PLA中20%木质素)复合长丝的性能。通过拉伸试验,差示扫描量热法,热重分析,扫描电子显微镜,细丝的傅立叶变换红外光谱以及3D打印样品的动态力学分析,研究了木质素在PLA和PEG中的含量以及Struktol在PLA_L20复合材料中的作用。2 wt%的PEG能够在PLA_L20复合材料的最大载荷下分别提高拉伸应力和伸长率19%和35%,

更新日期:2020-11-03
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