Traditional porous carbon (PC)-based supercapacitors (SCs) are generally stiff and heavy owing to their rigid components and bulky additives, such as binders, conducting materials, and current collectors. Herein, a porous (574.5 m² g⁻¹), conductive (83.1 S cm⁻¹), and flexible MXene (Ti₃C₂T_x)/cellulose nanofiber (CNF)/PC hybrid film is prepared by strong interfacial interactions among its components via a facile vacuum-filtration method. Three-dimensional PC provides abundant micropores for charge storage and considerable amount of meso/macropores for fast diffusion of ions. Two-dimensional Ti₃C₂T_x offers a significantly high conductivity of 2.6 × 10³ S cm⁻¹ and a good film-forming ability. A one-dimensional CNF ensures high mechanical properties with a tensile strength of 38.6 MPa for the hybrid film by binding the adjacent Ti₃C₂T_x flakes and PC. Additionally, the presence of CNF and PC increases the interlayer distance between Ti₃C₂T_x flakes, thereby providing more ion-accessible surface areas on Ti₃C₂T_x and creating open gaps for fast ion transport. Benefiting from these electrochemically attractive properties, this film is further employed as a free-standing electrode to fabricate a high-performance quasi-solid-state SC, which demonstrates an ultrathin thickness of 0.2 mm, a high flexibility, a significantly high areal capacitance of 143 mF cm⁻² at 0.1 mA cm⁻², and a large areal energy density of 2.4 μWh cm⁻² at 17.5 μW cm⁻², with a high retention of ∼50% even after increasing the power density by ∼100 fold. This work will pave the way for developing free-standing MXene-based hybrid films that simultaneously possess excellent conductivity, good mechanical properties, and large charge storage capacity for flexible and high-performance SCs.