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Study on apparent kinetics of NO oxidized by H2O2 with UV-enhancement
Chemical Engineering and Processing: Process Intensification ( IF 4.3 ) Pub Date : 2020-10-23 , DOI: 10.1016/j.cep.2020.108202
Yubing Liu , Zhigang Tang , Yujun Wang , Guiguang Chen , Qiqi Han , Zhenqiang Xie , Jianbing Li

The integrated removal technology of SO2, NOx and CO2 is an emerging low-cost flue gas purification technology, in which the oxidation of NO is the key to this technology. In view of the fact that the UV-enhanced NO oxidation by H2O2 has the advantages of simple process, good maneuverability and easy enlargement, a pilot system was established to explore the apparent kinetics of NO Oxidation. The influences of NO concentration in flue gas, dosage of H2O2, UV radiation intensity and temperature on the reaction were investigated sequentially. After regressing corresponding parameters based on experimental data, an apparent kinetic model to describe the NO oxidation by H2O2 enhanced by UV irradiation is obtained, which provides a reference for further design on a larger-scale plant.



中文翻译:

紫外线增强作用下H 2 O 2氧化NO的表观动力学研究

SO 2,NO x和CO 2的综合去除技术是一种新兴的低成本烟气净化技术,其中NO的氧化是该技术的关键。鉴于H 2 O 2对UV增强NO的氧化具有工艺简单,可操作性好和易于扩大的优点,因此建立了一个中试系统以探索NO氧化的表观动力学。烟气中NO浓度,H 2 O 2用量的影响,依次研究了UV辐射强度和反应温度。根据实验数据对相应参数进行回归后,得到一个表观动力学模型,描述了紫外线辐射增强的H 2 O 2引起的NO氧化,为进一步设计大型装置提供了参考。

更新日期:2020-10-30
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