Solvent induced enantioselectivity reversal is a rarely reported phenomenon in porous homochiral materials. Similar behaviour has been studied in chiral HPLC, where minor mobile phase modifications can induce elution order reversal. We report the first instance of solvent-induced enantioselectivity reversal for homochiral MOF ZnBLD, highlighting the complex enantioselectivity behaviour

中文翻译：

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手性金属有机骨架中溶剂诱导的对映选择性逆转

溶剂诱导的对映选择性逆转是多孔同手性材料中很少报道的现象。在手性HPLC中已经研究了类似的行为，其中较小的流动相修饰会导致洗脱顺序逆转。我们报告了第一例溶剂诱导的同手性MOF ZnBLD对映体选择性逆转，突出了复杂的对映体选择性行为