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Diiodine–Triethylsilane System: Reduction of N-Sulfonyl Aldimines to N-Alkylsulfonamides
Synlett ( IF 2 ) Pub Date : 2020-10-19 , DOI: 10.1055/s-0040-1706544
Jin Jiang 1, 2 , Lili Xiao 3 , Yu-Long Li 1
Affiliation  

Because molecular iodine and hydrosilanes are stable to both air and moisture, reactions using these reagents are easy to operate and require mild reaction conditions. Molecular iodine and a hydrosilane were used to reduce N-sulfonyl aldimines to the corresponding N-alkylsulfonamides. This transformation is a practical method for the synthesis of N-alkylsulfonamides.

中文翻译:

二碘-三乙基硅烷体系:将 N-磺酰基醛亚胺还原为 N-烷基磺酰胺

由于分子碘和氢硅烷对空气和湿气均稳定,因此使用这些试剂的反应易于操作且需要温和的反应条件。分子碘和氢硅烷用于将 N-磺酰基醛亚胺还原为相应的 N-烷基磺酰胺。这种转化是合成 N-烷基磺酰胺的实用方法。
更新日期:2020-10-19
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