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A review on hybrid and flexible CO2 gas sensors
Synthetic Metals ( IF 4.4 ) Pub Date : 2020-12-01 , DOI: 10.1016/j.synthmet.2020.116602
A. Molina , V. Escobar-Barrios , J. Oliva

Abstract Nowadays, the detection of CO2 gas is relevant in industry because it can provoke respiratory diseases if its concentration is high in the work-places. Also, it contributes to the greenhouse effect. The current CO2 sensors are based on rigid ceramic materials, which require high operating temperatures (200–600 °C), and high energy consumption (30–200 W). Due to these disadvantages, the hybrid and flexible sensors have emerged as an alternative to substitute the old technologies of ceramic-based sensors. These flexible sensors are more compact and light. Also, their energy consumption is very low (mW) and can operate at lower temperatures of 25–80 °C. Due to this new trend for CO2 sensors, we present in this review the general configuration and materials to construct hybrid and flexible CO2 sensors. Polyethylenimine (PEI), poly(3,4-ethylenedioxythiophene) (PEDOT), Polyethylene glycol (PEG) and polyaniline (PANI) polymers have been employed to fabricate hybrid sensors with a detection range from 1 to 10,000 ppm of CO2. In the case of sensors based on carbon materials such as graphene and carbon nanotubes, they have a detection range of 1–4000 ppm for CO2. Moreover, we discussed how the variations of parameters such as temperature, humidity, CO2 concentration and curvature radius (in the case of flexible sensors) affects the response times, recovery times and response percentage of the hybrid/flexible sensors. Furthermore, this review presents the current unsolved challenges for flexible CO2 sensors, which are limiting their use in commercial applications. Finally, our review emphasizes the opportunities of research for hybrid/flexible CO2 sensors.

中文翻译:

混合和灵活的 CO2 气体传感器综述

摘要 如今,CO2 气体的检测在工业中具有重要意义,因为如果其在工作场所的浓度高,它会引发呼吸系统疾病。此外,它有助于温室效应。当前的 CO2 传感器基于刚性陶瓷材料,需要高工作温度 (200–600 °C) 和高能耗 (30–200 W)。由于这些缺点,混合和柔性传感器已成为替代陶瓷传感器旧技术的替代方案。这些灵活的传感器更加小巧轻便。此外,它们的能耗非常低 (mW),可以在 25–80 °C 的较低温度下运行。由于 CO2 传感器的这一新趋势,我们在这篇综述中介绍了构建混合和灵活 CO2 传感器的一般配置和材料。聚乙烯亚胺 (PEI), 聚 (3, 4-亚乙基二氧噻吩) (PEDOT)、聚乙二醇 (PEG) 和聚苯胺 (PANI) 聚合物已被用于制造具有 1 至 10,000 ppm CO2 检测范围的混合传感器。对于基于碳材料(如石墨烯和碳纳米管)的传感器,它们对 CO2 的检测范围为 1–4000 ppm。此外,我们还讨论了温度、湿度、CO2 浓度和曲率半径(在柔性传感器的情况下)等参数的变化如何影响混合/柔性传感器的响应时间、恢复时间和响应百分比。此外,本综述提出了柔性 CO2 传感器目前尚未解决的挑战,这些挑战限制了它们在商业应用中的使用。最后,我们的评论强调了混合/柔性 CO2 传感器的研究机会。聚乙二醇 (PEG) 和聚苯胺 (PANI) 聚合物已被用于制造具有 1 至 10,000 ppm CO2 检测范围的混合传感器。对于基于碳材料(如石墨烯和碳纳米管)的传感器,它们对 CO2 的检测范围为 1–4000 ppm。此外,我们还讨论了温度、湿度、CO2 浓度和曲率半径(在柔性传感器的情况下)等参数的变化如何影响混合/柔性传感器的响应时间、恢复时间和响应百分比。此外,这篇综述提出了柔性 CO2 传感器目前尚未解决的挑战,这些挑战限制了它们在商业应用中的使用。最后,我们的评论强调了混合/柔性 CO2 传感器的研究机会。聚乙二醇 (PEG) 和聚苯胺 (PANI) 聚合物已被用于制造具有 1 至 10,000 ppm CO2 检测范围的混合传感器。对于基于碳材料(如石墨烯和碳纳米管)的传感器,它们对 CO2 的检测范围为 1–4000 ppm。此外,我们还讨论了温度、湿度、CO2 浓度和曲率半径(在柔性传感器的情况下)等参数的变化如何影响混合/柔性传感器的响应时间、恢复时间和响应百分比。此外,这篇综述提出了柔性 CO2 传感器目前尚未解决的挑战,这些挑战限制了它们在商业应用中的使用。最后,我们的评论强调了混合/柔性 CO2 传感器的研究机会。
更新日期:2020-12-01
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