当前位置: X-MOL 学术Chem. Heterocycl. Comp. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Reaction of N -benzyl azomethine ylide with aryl isothiocyanates: synthesis of ( Z )- N -aryl-3-benzylthiazolidine-5-imines
Chemistry of Heterocyclic Compounds ( IF 1.5 ) Pub Date : 2020-10-19 , DOI: 10.1007/s10593-020-02802-5
Evgeny M. Buev , Anna P. Osintseva , Vladimir S. Moshkin , Vyacheslav Ya. Sosnovskikh

The reaction of aryl isothiocyanates with nonstabilized azomethine ylides generated in situ by various methods was studied. It was established that the use of N-(methoxymethyl)-N-(trimethylsilylmethyl)benzylamine in the presence of trifluoroacetic acid in the role of a catalyst led to the formation of (Z)-N-aryl-3-benzylthiazolidin-5-imines in 22–47% yields.



中文翻译:

N-苄基偶氮甲亚胺叶立德与异硫氰酸芳基酯的反应:(Z)-N-芳基-3-苄基噻唑烷-5-亚胺的合成

研究了异硫氰酸芳基酯与通过各种方法原位生成的不稳定的甲亚胺基化物的反应。已经确定,在三氟乙酸的存在下,在催化剂的作用下使用N-(甲氧基甲基)-N-(三甲基甲硅烷基甲基)苄基胺导致形成(Z-N-芳基-3-苄基噻唑烷-5-亚胺的产率为22–47%。

更新日期:2020-10-19
down
wechat
bug