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Benzazoles: III. Synthesis and Transformations of 6-(Chlorosulfonyl)-1,3-benzothiazol-2(3 H )-ones
Russian Journal of Organic Chemistry ( IF 0.8 ) Pub Date : 2020-10-19 , DOI: 10.1134/s1070428020090031
D. A. Dushamov , Yu. R. Takhirov , R. Sh. Kuryazov , N. S. Mukhamedov

Abstract

Treatment of 1,3-benzothiazol-2(3H)-one and its 3-methyl derivative with chlorosulfonic acid afforded the corresponding 2-oxo-2,3-dihydro-1,3-benzothiazole-6-sulfonyl chlorides which reacted with water, alcohols, and amines to give 2-oxo-2,3-dihydro-1,3-benzothiazole-6-sulfonic acids and their esters and amides.



中文翻译:

苯唑:III。6-(氯磺酰基)-1,3-苯并噻唑-2(3 H)-ones的合成与转化

摘要

用氯磺酸处理1,3-苯并噻唑-2(3 H)-1及其3-甲基衍生物,得到相应的2-氧代-2,3-二氢-1,3-苯并噻唑-6-磺酰氯,与用水,醇和胺制得2-氧代-2,3-二氢-1,3-苯并噻唑-6-磺酸及其酯和酰胺。

更新日期:2020-10-19
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