Chemical Physics Letters ( IF 2.8 ) Pub Date : 2020-10-17 , DOI: 10.1016/j.cplett.2020.138088 Krishna Prasad Aryal , Hae Kyung Jeong
A novel modified electrochemical electrode, nickel (Ni) decorated on reduced graphite oxide (rGO)/oxidized carbon nanofiber (oxCNF), Ni/rGO-oxCNF, was synthesized for the electrochemical detection of dopamine (DA). Synthesized electrode displayed distinct peak at 0.21 V in the detection of DA with differential pulse voltammetry. It also showed excellent selectivity in presence of ascorbic acid and uric acid, with wide separation potential. High sensitivity of 1.64 µA/µM, for the concentration range (10 µM-16 µM) of DA and limit of detection of 0.6 µM were obtained. The modified electrode, therefore, could be a good alternative for electrochemical detection of DA.
中文翻译:
镍修饰的石墨氧化物和碳纳米纤维表面用于多巴胺的电化学检测
合成了一种新型的修饰电化学电极,在还原的氧化石墨(rGO)/氧化碳纳米纤维(oxCNF)上修饰的镍(Ni),Ni / rGO-oxCNF用于多巴胺(DA)的电化学检测。在差分脉冲伏安法检测DA时,合成电极在0.21 V处显示出明显的峰。在抗坏血酸和尿酸的存在下,它也显示出极好的选择性,具有很强的分离潜力。对于DA的浓度范围(10 µM-16 µM),检测灵敏度为1.64 µA / µM,检测极限为0.6 µM。因此,修饰的电极可能是DA电化学检测的良好选择。