A superhydrophobic composite coating was facilely constructed based on MOF (ZIF-8) nanoparticles and organic resin. Hydrophilic ZIF-8 nanoparticles with hydroxyl group were firstly prepared in aqueous media at room temperature, and then modified with low surface energy perfluorooctyltriethoxysilane (POTS) through hydrolytic condensation to give a superhydrophobic paint. Additionally, epoxy resin (EP) was innovatively introduced as adhesive layer to improve the robustness and adhesive force of the superhydrophobic coating. The as-prepared ZIF-8/POTS/EP composite coating showed high water-repellency (water contact angle = 168.2 °), mechanical and chemical robustness, and durability that it could maintain the superhydrophobicity after weathering in air for 300 days or immersing in 3.5 wt.% NaCl aqueous solution for 60 days. The superhydrophobic composite coating also possessed excellent performance in self-cleaning, corrosion resistance, anti-icing and loading-increasing. Noteworthily, for the corrosion resistance, the ZIF-8/POTS/EP coating could increase the impedance modulus (at 0.01 Hz) of Q235 steel by about 7 orders of magnitude after immersion in 3.5 wt.% NaCl aqueous solution for 7 days. We believe that this work can not only promote the effortless and large-scale preparation of superhydrophobic surface and their practical applications in future, but also provide a novel way for applying MOF materials into more fields.

基于MOF（ZIF-8）纳米颗粒和有机树脂，可轻松构建超疏水复合涂层。首先在室温下在水性介质中制备具有羟基的亲水性ZIF-8纳米粒子，然后通过低表面能全氟辛基三乙氧基硅烷（POTS）进行水解缩合改性，得到超疏水性涂料。此外，创新地引入了环氧树脂（EP）作为粘合层，以提高超疏水涂层的坚固性和粘合力。所制备的ZIF-8 / POTS / EP复合涂层显示出高拒水性（水接触角= 168.2°），机械和化学强度以及耐用性，可以在空气中风化300天或浸入水中后保持超疏水性。 3.5重量％的NaCl水溶液60天。该超疏水复合涂层在自清洁，耐腐蚀，防冰和增加载荷方面也具有优异的性能。值得注意的是，就抗腐蚀性而言，将ZIF-8 / POTS / EP涂层浸入3.5 wt。％NaCl水溶液7天后，可使Q235钢的阻抗模量（在0.01 Hz时）提高约7个数量级。我们相信，这项工作不仅可以促进超疏水表面的简便，大规模制备及其在未来的实际应用，而且为将MOF材料应用于更多领域提供了一种新颖的途径。在将Q235钢浸入3.5 wt。％的NaCl水溶液中7天后，将其大约7个数量级的QHz钢（01 Hz）。我们相信，这项工作不仅可以促进超疏水表面的简便，大规模制备及其在未来的实际应用，而且为将MOF材料应用于更多领域提供了一种新颖的途径。在将Q235钢浸入3.5 wt。％的NaCl水溶液中7天后，将其大约7个数量级的QHz钢（01 Hz）。我们相信，这项工作不仅可以促进超疏水表面的简便，大规模制备及其在未来的实际应用，而且为将MOF材料应用于更多领域提供了一种新颖的途径。